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A back titration is useful if the endpoint of the reverse titration is easier to identify than the endpoint of the normal titration, as with precipitation reactions. Back titrations are also useful if the reaction between the analyte and the titrant is very slow, or when the analyte is in a non-soluble solid. [44]
An example of back titration, the Volhard method, named after Jacob Volhard, involves the addition of excess silver nitrate to the analyte; the silver chloride is filtered, and the remaining silver nitrate is titrated against ammonium thiocyanate, [1] with ferric ammonium sulfate as an indicator which forms blood-red [Fe(OH 2) 5 (SCN)] 2+ at the end point:
Fig. 15. Titration plot of back-titration of excess EDTA with Cu(II) in NH 3 /NH 4 Cl buffered solution. Direct EDTA titrations with metal ions are possible when reaction kinetics are fast, for example zinc, copper, calcium and magnesium. However, with slower reaction kinetics such as those exhibited by cobalt and nickel, back-titrations are used.
Iodometry, known as iodometric titration, is a method of volumetric chemical analysis, a redox titration where the appearance or disappearance of elementary iodine indicates the end point. Note that iodometry involves indirect titration of iodine liberated by reaction with the analyte, whereas iodimetry involves direct titration using iodine as ...
If boric acid (or some other weak acid) was used, direct acid–base titration is done with a strong acid of known concentration. HCl or H 2 SO 4 can be used. Indirect back titration is used instead if strong acids were used to make the standard acid solution: strong base of known concentration (like NaOH) is used to neutralize the solution. In ...
The chief advantage over other types of titration is the selectivity offered by the electrode potential, as well as by the choice of titrant. For instance, lead ion is reduced at a potential of -0.60 V (relative to the saturated calomel electrode), while zinc ions are not; this allows the determination of lead in the presence of zinc. Clearly ...
In the direct method, just enough of the reagents will be added to completely use up all of the water. At this point in the titration, the current approaches zero. It is then possible to relate the amount of reagents used to the amount of water in the system via stoichiometry. The back-titration method is similar, but involves the addition of ...
The history of acid-base titration dates back to the late 19th century when advancements in analytical chemistry fostered the development of systematic techniques for quantitative analysis. [5] The origins of titration methods can be linked to the work of chemists such as Karl Friedrich Mohr in the mid-1800s. [5]
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