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Hydrogen iodide (HI) is a diatomic molecule and hydrogen halide. Aqueous solutions of HI are known as hydroiodic acid or hydriodic acid, a strong acid . Hydrogen iodide and hydroiodic acid are, however, different in that the former is a gas under standard conditions, whereas the other is an aqueous solution of the gas .
This method starts with a solution of hydrogen peroxide and sulfuric acid. To this a solution containing potassium iodide, sodium thiosulfate, and starch is added. There are two reactions occurring simultaneously in the solution. In the first, slow reaction, iodine is produced: H 2 O 2 + 2 I − + 2 H + → I 2 + 2 H 2 O
In the classic Finkelstein reaction, an alkyl chloride or an alkyl bromide is converted to an alkyl iodide by treatment with a solution of sodium iodide in acetone. Sodium iodide is soluble in acetone and sodium chloride and sodium bromide are not. [29] The reaction is driven toward products by mass action due to the precipitation of the ...
I 2 dissolves in the iodide-containing solution to give triiodide ions (I 3 −), which have a dark brown color. The triiodide ion solution is then titrated against standard thiosulfate solution to give iodide again using starch indicator: I − 3 + 2 e − ⇌ 3 I − (E 0 = +0.54 V) Together with reduction potential of thiosulfate: [1]
This is an accepted version of this page This is the latest accepted revision, reviewed on 16 February 2025. This article is about the chemical element. For other uses, see Iodine (disambiguation). Chemical element with atomic number 53 (I) Iodine, 53 I Iodine Pronunciation / ˈ aɪ ə d aɪ n, - d ɪ n, - d iː n / (EYE -ə-dyne, -din, -deen) Appearance lustrous metallic gray solid ...
The initial aqueous solution contains hydrogen peroxide, an iodate, divalent manganese (Mn 2+) as catalyst, a strong chemically unreactive acid (sulphuric acid (H 2 SO 4) or perchloric acid (HClO 4) are good), and an organic compound with an active ("enolic") hydrogen atom attached to carbon which will slowly reduce free iodine (I 2) to iodide (I −).
It is an aqueous solution of hydrogen iodide with the chemical formula H I. It is a strong acid, in which hydrogen iodide is ionized completely in an aqueous solution. Concentrated aqueous solutions of hydrogen iodide are usually 48% to 57% HI by mass. [2] An oxidized solution of hydriodic acid.
About 50 ml of concentrated (>12%) [5] hydrogen peroxide is first mixed with liquid soap or dishwashing detergent. Then, a catalyst, often around 10 ml potassium iodide solution or catalase from baker's yeast, is added to make the hydrogen peroxide decompose very quickly. Hydrogen peroxide breaks down into oxygen and water.