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Acetophenone is formed as a byproduct of the cumene process, the industrial route for the synthesis of phenol and acetone.In the Hock rearrangement of isopropylbenzene hydroperoxide, migration of a methyl group rather than the phenyl group gives acetophenone and methanol as a result of an alternate rearrangement of the intermediate:
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Phenacyl chloride, also commonly known as chloroacetophenone, is a substituted acetophenone.It is a useful building block in organic chemistry.Apart from that, it has been historically used as a riot control agent, where it is designated CN. [5]
The initial product is a thioamide for example that of acetophenone [7] which can again be hydrolyzed to the amide. The reaction is named after Karl Kindler The Kindler modification of the Willgerodt rearrangement. A possible reaction mechanism for the Kindler variation is depicted below: [8]
Acetone (2-propanone or dimethyl ketone) is an organic compound with the formula (CH 3) 2 CO. [22] It is the simplest and smallest ketone (>C=O).It is a colorless, highly volatile, and flammable liquid with a characteristic pungent odour, very reminiscent of the smell of pear drops.
Acetophenone carboxylase (EC 6.4.1.8) is an enzyme with systematic name acetophenone:carbon-dioxide ligase (ADP-forming). [1] This enzyme catalyses the following chemical reaction 2 ATP + acetophenone + HCO 3 − + H 2 O + H + ⇌ {\displaystyle \rightleftharpoons } 2 ADP + 2 phosphate + 3-oxo-3-phenylpropanoate
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