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When applied to atomic orbitals, this means that the energy differences between states are also discrete. A transition between these states (i.e., an electron absorbing or emitting a photon) can thus happen only if the photon has an energy corresponding with the exact energy difference between said states. Consider two states of the hydrogen atom:
The Bohr model of the hydrogen atom (Z = 1) or a hydrogen-like ion (Z > 1), where the negatively charged electron confined to an atomic shell encircles a small, positively charged atomic nucleus and where an electron jumps between orbits, is accompanied by an emitted or absorbed amount of electromagnetic energy (hν). [1]
A photon (from Ancient Greek φῶς, φωτός (phôs, phōtós) 'light') is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force.
For an electron to transition between two different states, e.g. ground state to first excited state, it must absorb or emit a photon at an energy matching the difference in the potential energy of those levels, according to the Niels Bohr model, what can be precisely calculated by the Schrödinger equation. Electrons jump between orbitals in a ...
To escape the atom, the energy of the electron must be increased above its binding energy to the atom. This occurs, for example, with the photoelectric effect, where an incident photon exceeding the atom's ionization energy is absorbed by the electron. [124]: 127–132 The orbital angular momentum of electrons is quantized. Because the electron ...
Feynman diagram of electron/positron annihilation. The electron–positron annihilation interaction: e + + e − → 2γ. has a contribution from the second order Feynman diagram: In the initial state (at the bottom; early time) there is one electron (e −) and one positron (e +) and in the final state (at the top; late time) there are two ...
In a neutral atom, the system will emit a photon of the difference in energy. However, if the lower state is in an inner shell, a phenomenon known as the Auger effect may take place where the energy is transferred to another bound electrons causing it to go into the continuum. This allows one to multiply ionize an atom with a single photon.
In materials with a large exciton binding energy, it is possible for a photon to have just barely enough energy to create an exciton (bound electron–hole pair), but not enough energy to separate the electron and hole (which are electrically attracted to each other). In this situation, there is a distinction between "optical band gap" and ...