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At 30 °C the relative reaction rates of primary, secondary and tertiary hydrogen atoms are in a relative ratio of approximately 1 to 3.25 to 4.43. The C-C bonds remain unaffected. [9] [10] Upon radiation the reaction involves alkyl and chlorine radicals following a chain reaction according to the given scheme:
Chemical pulping involves dissolving lignin in order to extract the cellulose from the wood fiber. The different processes of chemical pulping include the Kraft process, which uses caustic soda and sodium sulfide and is the most common; alternatively, the use of sulfurous acid is known as the sulfite process, the neutral sulfite semichemical is treated as a third process separate from sulfite ...
For example, the industrial production of chloroethane proceeds by the reaction of ethylene with HCl: [citation needed] H 2 C=CH 2 + HCl → CH 3 CH 2 Cl. In oxychlorination, hydrogen chloride instead of the more expensive chlorine is used for the same purpose: CH 2 =CH 2 + 2 HCl + 1 ⁄ 2 O 2 → ClCH 2 CH 2 Cl + H 2 O.
This reaction mechanism is supported by the observation that addition of pyridine to the reaction leads to inversion. The reasoning behind this finding is that pyridine reacts with the intermediate sulfite replacing chlorine. The dislodged chlorine has to resort to nucleophilic attack from the rear as in a regular nucleophilic substitution. [3]
The grade of chlorine-based bleaches is often expressed as percent active chlorine. One gram of 100% active chlorine bleach has the same bleaching power as one gram of elemental chlorine. The most common chlorine-based bleaches are: Sodium hypochlorite (NaClO), usually as a 3–6% solution in water, usually called "liquid bleach" or just "bleach".
The reaction has to be carried out in a slightly alkaline medium (pH 8.5–11). The acting chlorinating agent in this reaction is hypochlorous acid (HOCl), which has to be generated by protonation of hypochlorite, and then reacts in a nucleophilic substitution of the hydroxyl against the amino group. The reaction occurs quickest at around pH 8.
A halogen addition reaction is a simple organic reaction where a halogen molecule is added to the carbon–carbon double bond of an alkene functional group. [1] The general chemical formula of the halogen addition reaction is: C=C + X 2 → X−C−C−X (X represents the halogens bromine or chlorine, and in this case, a solvent could be CH 2 ...
Alternatively, when the reaction of the solid and the transport agent is endothermic, the solid is transported from a hot zone to a cooler one. For example: Fe 2 O 3 + 6 HCl ⇌ Fe 2 Cl 6 + 3 H 2 O ΔH rxn > 0 (endothermic) The sample of iron(III) oxide is maintained at 1000 °C, and the product is grown at 750 °C. HCl is the transport agent.