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Scandium is a chemical element with the symbol Sc and atomic number 21. It is a silvery-white metallic d-block element. Historically, it has been classified as a rare-earth element, [9] together with yttrium and the lanthanides. It was discovered in 1879 by spectral analysis of the minerals euxenite and gadolinite from Scandinavia. [10]
In all four halides, the scandium is 6-coordinated. They can be prepared by reacting scandium oxide or scandium hydroxide with the corresponding acid: [3] Sc(OH) 3 + 3 HX → ScX 3 + 3 H 2 O. The halides are Lewis acids; for example, ScF 3 dissolves in a solution containing excess fluoride ion to form [ScF 6] 3−. The coordination number 6 is ...
The reaction of scandium trichloride with two equivalents of sodium cyclopentadienide (NaCp) produces the chloride-bridged dimer: 2 ScCl 3 + 4 NaCp → [Cp 2 Sc(μ-Cl)] 2 + 4 NaCl. Cp 3 Sc is a polymer wherein one third of the Cp ligands serving as bridging ligands. [5] Bulkier cyclopentadienide ligands give monoscandium derivatives, e.g. (C 5 ...
Download as PDF; Printable version; In other projects Wikimedia Commons; ... Pages in category "Scandium" The following 5 pages are in this category, out of 5 total.
Download QR code; Print/export Download as PDF; Printable version; In other projects ... Scandium perchlorate is an inorganic compound with the chemical formula Sc ...
Download as PDF; Printable version; In other projects Wikidata item; ... Pages in category "Scandium minerals" The following 7 pages are in this category, out of 7 ...
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Scandium acetylacetonate is the coordination complex with the formula Sc(C 5 H 7 O 2) 3 where [C 5 H 7 O 2] − refers to acetylacetonate. It is a volatile white solid that is soluble in benzene. The complex features Sc(III) with octahedral molecular geometry. [1] It was first prepared by treating scandium nitrate with acetylacetone in the ...