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Diagram of the electric field of a light wave (blue), linear-polarized along a plane (purple line), and consisting of two orthogonal, in-phase components (red and green waves) In electrodynamics , linear polarization or plane polarization of electromagnetic radiation is a confinement of the electric field vector or magnetic field vector to a ...
Tafel plot for an anodic process (). The Tafel equation is an equation in electrochemical kinetics relating the rate of an electrochemical reaction to the overpotential. [1] The Tafel equation was first deduced experimentally and was later shown to have a theoretical justification.
Linear potential sweep In analytical chemistry , linear sweep voltammetry is a method of voltammetry where the current at a working electrode is measured while the potential between the working electrode and a reference electrode is swept linearly in time.
In a homogeneous, linear, non-dispersive and isotropic dielectric medium, the polarization is aligned with and proportional to the electric field E: [7] =, where ε 0 is the electric constant , and χ is the electric susceptibility of the medium.
The first two diagrams below trace the electric field vector over a complete cycle for linear polarization at two different orientations; these are each considered a distinct state of polarization (SOP). The linear polarization at 45° can also be viewed as the addition of a horizontally linearly polarized wave (as in the leftmost figure) and a ...
In contrast to that, the waves of linear-polarized light oscillate in parallel planes. [3] If light encounters a polarizer, only the part of the light that oscillates in the defined plane of the polarizer may pass through. That plane is called the plane of polarization. The plane of polarization is turned by optically active compounds.
In electrochemistry, polarization is a collective term for certain mechanical side-effects (of an electrochemical process) by which isolating barriers develop at the interface between electrode and electrolyte. These side-effects influence the reaction mechanisms, as well as the chemical kinetics of corrosion and metal deposition.
The upper graph shows the current density as function of the overpotential η . The anodic and cathodic current densities are shown as j a and j c, respectively for α=α a =α c =0.5 and j 0 =1mAcm −2 (close to values for platinum and palladium).
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