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Ionic radius, r ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the cation and anion gives the distance between the ions in a crystal lattice.
In condensed matter physics and inorganic chemistry, the cation-anion radius ratio can be used to predict the crystal structure of an ionic compound based on the relative size of its atoms. It is defined as the ratio of the ionic radius of the positively charged cation to the ionic radius of the negatively charged anion in a cation-anion ...
Cations and anions are measured by their ionic radius and they differ in relative size: "Cations are small, most of them less than 10 −10 m (10 −8 cm) in radius. But most anions are large, as is the most common Earth anion, oxygen.
For typical ionic solids, the cations are smaller than the anions, and each cation is surrounded by coordinated anions which form a polyhedron.The sum of the ionic radii determines the cation-anion distance, while the cation-anion radius ratio + / (or /) determines the coordination number (C.N.) of the cation, as well as the shape of the coordinated polyhedron of anions.
In inorganic chemistry, Fajans' rules, formulated by Kazimierz Fajans in 1923, [1] [2] [3] are used to predict whether a chemical bond will be covalent or ionic, and depend on the charge on the cation and the relative sizes of the cation and anion. They can be summarized in the following table:
This arrangement reflects the ion's charge density and size, leading to strong ion-dipole interactions with water molecules. In contrast, chloride ions generally have a hydration number closer to 6 due to their larger ionic radius and more distributed charge, which allows them to stabilize a larger number of water molecules in their hydration ...
The name of the cation (the unmodified element name for monatomic cations) comes first, followed by the name of the anion. [ 100 ] [ 101 ] For example, MgCl 2 is named magnesium chloride , and Na 2 SO 4 is named sodium sulfate ( SO 2−
In chemistry, ion association is a chemical reaction whereby ions of opposite electric charge come together in solution to form a distinct chemical entity. [1] [2] Ion associates are classified, according to the number of ions that associate with each other, as ion pairs, ion triplets, etc. Ion pairs are also classified according to the nature of the interaction as contact, solvent-shared or ...