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Cyclohexane has two crystalline phases. The high-temperature phase I, stable between 186 K and the melting point 280 K, is a plastic crystal, which means the molecules retain some rotational degree of freedom. The low-temperature (below 186 K) phase II is ordered.
Phase behavior Triple point: 279.48 K (6.33 °C), 5.388 kPa [3] Critical point: 554 K (281 °C), 4070 kPa Std enthalpy change of fusion, Δ fus H o: 2.68 kJ/mol crystal I → liquid Std entropy change of fusion, Δ fus S o: 9.57 J/(mol·K) crystal I → liquid Std enthalpy change of vaporization, Δ vap H o: 32 kJ/mol Std entropy change of ...
The phase behavior of polymer solutions is an important property involved in the development and design of most polymer-related processes. Partially miscible polymer solutions often exhibit two solubility boundaries, the upper critical solution temperature (UCST) and the LCST, both of which depend on the molar mass and the pressure. At ...
e.g. iso-octane, Aliquat 336 (methyltrioctylammonium chloride, a phase transfer catalyst), water. or: cyclohexane, bmim-PF 6 (an ionic liquid), water; Hydrophobic ionic liquid – water – hydrocarbon systems e.g. 1-butyl-3-methylimidazolium hexafluorophosphate – water – cyclohexane
A mobile phase in reversed-phase chromatograpy consists of mixtures of water or aqueous buffers, to which organic solvents are added, to elute analytes from a reversed-phase column in a selective manner. [7] [27] The added organic solvents must be miscible with water, and the two most common organic solvents used are acetonitrile and methanol.
The dipole moment of 18-crown-6 is solvent- and temperature-dependent. Below 25 °C, the dipole moment of 18-crown-6 is 2.76 ± 0.06 D in cyclohexane and 2.73 ± 0.02 in benzene. [2] The synthesis of the crown ethers led to the awarding of the Nobel Prize in Chemistry to Charles J. Pedersen.
U.S. President Donald Trump stripped Secret Service protection on Tuesday from his former national security adviser, John Bolton, who became the target of an alleged Iranian murder plot after he ...
A monosubstituted cyclohexane is one in which there is one non-hydrogen substituent in the cyclohexane ring. The most energetically favorable conformation for a monosubstituted cyclohexane is the chair conformation with the non-hydrogen substituent in the equatorial position because it prevents high steric strain from 1,3 diaxial interactions. [11]