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Boric acid is a weak acid, with pK a (the pH at which buffering is strongest because the free acid and borate ion are in equal concentrations) of 9.24 in pure water at 25 °C. But apparent p K a is substantially lower in swimming pool or ocean waters because of interactions with various other molecules in solution.
Trimethyl borate is a popular borate ester used in organic synthesis. Borate esters form spontaneously when treated with diols such as sugars and the reaction with mannitol forms the basis of a titrimetric analytical method for boric acid. Metaborate esters show considerable Lewis acidity and can initiate epoxide polymerization reactions. [4]
Borate anions are largely in the form of the undissociated acid in aqueous solution at physiological pH. No further metabolism occurs in either animals or plants. In animals, boric acid/borate salts are essentially completely absorbed following oral ingestion. Absorption occurs via inhalation, although quantitative data are unavailable.
Sassolite is a borate mineral, specifically the mineral form of boric acid. It is usually white to gray, and colourless in transmitted light. It can also take on a yellow colour from sulfur impurities, or brown from iron oxides. [2]
Borate buffered saline (abbreviated BBS) is a buffer used in some biochemical techniques to maintain the pH within a relatively narrow range. Borate buffers have an alkaline buffering capacity in the 8–10 range. Boric acid has a pK a of 9.14 at 25 °C.
When orthoborate salts are dissolved in water, the anion converts mostly to boric acid B(OH) 3 and other hydrogen-containing borate anions, mainly tetrahydroxyborate [B(OH) 4] −. The reactions of orthoborate in solution are therefore mostly those of these compounds.
LB buffer, also known as lithium borate buffer, is a buffer solution used in agarose electrophoresis, typically for the separation of nucleic acids such as DNA and RNA. It is made up of Lithium borate ( lithium hydroxide monohydrate and boric acid ).
Sodium perborate hydrolyzes (i.e. breaks down in contact with water), producing hydrogen peroxide and borate: [3] (HO) 2 B] 2 (OO) 2) 2− + 2 H 2 O ⇌ 2 [(HO) 2 B(OH)(OOH)] − The resulting hydroperoxide then enter in equilibrium with boric acid B(OH) 3, hydrogen peroxide H 2 O 2, the hydroperoxyl anion − OOH, and the tetrahydroxyborate anion [B(OH) 4] −: [2]