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Process Safety Management of Highly Hazardous Chemicals is a regulation promulgated by the U.S. Occupational Safety and Health Administration (OSHA). [1] It defines and regulates a process safety management (PSM) program for plants using, storing, manufacturing, handling or carrying out on-site movement of hazardous materials above defined amount thresholds.
Prior to bringing regulations in line with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) in 2012, OSHA considered flammable liquids to be those with a flash point below 37.8 °C/100 °F. Those with flash points above 37.8 °C/100 °F and below 93.3 °C/200 °F were classified as combustible liquids.
Class 3: Flammable Liquids A flammable liquid is a liquid having a flash point of not more than 60 °C (140 °F), or any material in a liquid phase with a flash point at or above 37.8 °C (100 °F) that is intentionally heated and offered for transportation or transported at or above its flash point in a bulk packaging. The following exceptions ...
Flammable liquids are categorized by flammability, from Category 1 with flash point < 23 °C and initial boiling point < 35 °C to Category 4 with flash point > 60 °C and < 93 °C. Flammable solids are classified as solid substances which are readily combustible or may contribute to a fire through friction, and ignitable metal powders. They ...
2.1 Flammable Gas: Gases which ignite on contact with an ignition source, such as acetylene, hydrogen, and propane. 2.2 Non-Flammable Gases: Gases which are neither flammable nor poisonous. Includes the cryogenic gases/liquids (temperatures of below -100 °C) used for cryopreservation and rocket fuels, such as nitrogen, neon, and carbon dioxide.
Prior to 2012, OSHA's classification of flammable and combustible liquids in regulation 1910.106, was nearly identical to the National Fire Protective Association (NFPA) Flammable and Combustible Liquids Code, NFPA 30.
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