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A plot of typical polymer solution phase behavior including two critical points: a LCST and an UCST. The liquid–liquid critical point of a solution, which occurs at the critical solution temperature, occurs at the limit of the two-phase region of the phase diagram. In other words, it is the point at which an infinitesimal change in some ...
A critical point of a function of a single real variable, f (x), is a value x 0 in the domain of f where f is not differentiable or its derivative is 0 (i.e. ′ =). [2] A critical value is the image under f of a critical point.
After establishing the critical points of a function, the second-derivative test uses the value of the second derivative at those points to determine whether such points are a local maximum or a local minimum. [1] If the function f is twice-differentiable at a critical point x (i.e. a point where f ′ (x) = 0), then:
At the remaining critical point (0, 0) the second derivative test is insufficient, and one must use higher order tests or other tools to determine the behavior of the function at this point. (In fact, one can show that f takes both positive and negative values in small neighborhoods around (0, 0) and so this point is a saddle point of f .)
A line, usually vertical, represents an interval of the domain of the derivative.The critical points (i.e., roots of the derivative , points such that () =) are indicated, and the intervals between the critical points have their signs indicated with arrows: an interval over which the derivative is positive has an arrow pointing in the positive direction along the line (up or right), and an ...
Critical variables are defined, for example in thermodynamics, in terms of the values of variables at the critical point. On a PV diagram, the critical point is an inflection point . Thus: [ 1 ]
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This fold develops from a critical point defined by specific values of pressure, temperature, and molar volume. Because the surface is plotted using dimensionless variables (formed by the ratio of each property to its respective critical value), the critical point is located at the coordinates (,,). When drawn using these dimensionless axes ...