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In mathematics and physics, the heat equation is a parabolic partial differential equation. The theory of the heat equation was first developed by Joseph Fourier in 1822 for the purpose of modeling how a quantity such as heat diffuses through a given region. Since then, the heat equation and its variants have been found to be fundamental in ...
[1] [2] [3] A more fundamental statement was later labelled as the zeroth law after the first three laws had been established. The zeroth law of thermodynamics defines thermal equilibrium and forms a basis for the definition of temperature: if two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium ...
In the mathematical study of heat conduction and diffusion, a heat kernel is the fundamental solution to the heat equation on a specified domain with appropriate boundary conditions. It is also one of the main tools in the study of the spectrum of the Laplace operator , and is thus of some auxiliary importance throughout mathematical physics .
The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions.A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter (or 'downhill' in terms of the temperature gradient).
The author then explains how heat is defined or measured by calorimetry, in terms of heat capacity, specific heat capacity, molar heat capacity, and temperature. [ 42 ] A respected text disregards the Carathéodory's exclusion of mention of heat from the statement of the first law for closed systems, and admits heat calorimetrically defined ...
A representation of Hess's law (where H represents enthalpy) Hess's law of constant heat summation, also known simply as Hess's law, is a relationship in physical chemistry and thermodynamics [1] named after Germain Hess, a Swiss-born Russian chemist and physician who published it in 1840.
The defining equation for thermal conductivity is =, where is the heat flux, is the thermal conductivity, and is the temperature gradient. This is known as Fourier's law for heat conduction. Although commonly expressed as a scalar , the most general form of thermal conductivity is a second-rank tensor .
Only one equation of state will not be sufficient to reconstitute the fundamental equation. All equations of state will be needed to fully characterize the thermodynamic system. Note that what is commonly called "the equation of state" is just the "mechanical" equation of state involving the Helmholtz potential and the volume: