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However, high-strength adhesives have high surface energy. Thus, they bond poorly to low-surface-energy polymers or other materials. To solve this problem, surface treatment can be used to increase the surface energy as a preparation step before adhesive bonding.
Structural adhesives can be used to create load-bearing joints. Although many adhesives such as sealants, hot melt adhesives and even acrylic foam tapes can bear loads, the term structural adhesive is typically used where joints will have lap shear strength greater than 1450 psi. [3] The different types of structural adhesives are: Epoxies
Styrene block copolymers (SBC), also called styrene copolymer adhesives and rubber-based adhesives, have good low-temperature flexibility, high elongation, and high heat resistance. They are frequently used in hot melt adhesive applications, where the composition retains tack even when solidified; however non-pressure-sensitive formulations are ...
The high-MW ones require sophisticated extruders and are used as high-performance structural adhesives. The presence of hydrogen bonds between the polymer chains gives polyamides a high strength at even low molecular weights, in comparison with other polymers. Hydrogen bonds also provide retention of most of the adhesive strength up almost to ...
However, pressure-sensitive adhesives used in double-sided adhesive tapes, rapidly curing "superglue" cyanoacrylate, and many light-curing adhesives do achieve significant initial strength after completion of the joining process or very shortly thereafter, although not their ultimate strength required for further processing of the glued assembly.
However even if a surface has high energy, contaminants on the surface can interfere with the adhesive's ability to bond to the surface. The presence of contaminants such as dust, paper, and oils will reduce the contact area for the adhesives and lower the adhesives bonding strength.