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The molar volume of gases around STP and at atmospheric pressure can be calculated with an accuracy that is usually sufficient by using the ideal gas law. The molar volume of any ideal gas may be calculated at various standard reference conditions as shown below: V m = 8.3145 × 273.15 / 101.325 = 22.414 dm 3 /mol at 0 °C and 101.325 kPa
Gas undergoes a slight expansion when the temperature is raised from 15 °C (59 °F) to 60 °F and this expansion is built into the above factor for gas. The standard temperature and pressure (STP) for gas varies depending on the particular code being used. [2] It is just as important to know the standard pressure as the temperature.
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
For gases, departure from 3 R per mole of atoms is generally due to two factors: (1) failure of the higher quantum-energy-spaced vibration modes in gas molecules to be excited at room temperature, and (2) loss of potential energy degree of freedom for small gas molecules, simply because most of their atoms are not bonded maximally in space to ...
For a substance X with a specific volume of 0.657 cm 3 /g and a substance Y with a specific volume 0.374 cm 3 /g, the density of each substance can be found by taking the inverse of the specific volume; therefore, substance X has a density of 1.522 g/cm 3 and substance Y has a density of 2.673 g/cm 3. With this information, the specific ...
One example of standard conditions for the calculation of SCCM is = 0 °C (273.15 K) [1] and = 1.01 bar (14.72 psia) and a unity compressibility factor = 1 (i.e., an ideal gas is used for the definition of SCCM). [2] This example is for the semi-conductor-manufacturing industry.
Under STP, a reaction between three cubic meters of hydrogen gas and one cubic meter of nitrogen gas will produce about two cubic meters of ammonia.. The law of combining volumes states that when gases chemically react together, they do so in amounts by volume which bear small whole-number ratios (the volumes calculated at the same temperature and pressure).
To denote an amount of substance, the 'cm 3 STP ' is standard cubic centimeter, which is a unit of amount of substance rather than a unit of volume. It represents the number of gas molecules or moles that would occupy one cubic centimeter at standard temperature and pressure , as calculated via the ideal gas law .