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The reduction of nitro compounds are chemical reactions of wide interest in organic chemistry. The conversion can be effected by many reagents. The nitro group was one of the first functional groups to be reduced. Alkyl and aryl nitro compounds behave differently. Most useful is the reduction of aryl nitro compounds.
Moisture vapor transmission rate (MVTR), also water vapor transmission rate (WVTR), is a measure of the passage of water vapor through a substance. It is a measure of the permeability for vapor barriers. There are many industries where moisture control is critical.
Direct reduction from nitrate to ammonium, a process known as dissimilatory nitrate reduction to ammonium or DNRA, [6] is also possible for organisms that have the nrf-gene. [ 7 ] [ 8 ] This is less common than denitrification in most ecosystems as a means of nitrate reduction.
The Béchamp reduction (or Béchamp process) is a chemical reaction that converts aromatic nitro compounds to their corresponding anilines using iron as the reductant: [1] 4 C 6 H 5 NO 2 + 9 Fe + 4 H 2 O → 4 C 6 H 5 NH 2 + 3 Fe 3 O 4. This reaction was once a major route to aniline, but catalytic hydrogenation is the preferred method. [2]
If the fluid is a liquid, a different type of limiting condition (also known as choked flow) occurs when the venturi effect acting on the liquid flow through the restriction causes a decrease of the liquid pressure beyond the restriction to below that of the liquid's vapor pressure at the prevailing liquid temperature.
Zinin reaction or Zinin reduction involves reduction of nitro aromatic compounds to the amines using sodium sulfide. [1] It is used to convert nitrobenzenes to anilines. [2] [3] The reaction selectively reduces nitro groups in the presence of other easily reduced functional groups (e.g., aryl halides and C=C bonds) are present in the molecule.
Denitrification is the reduction of nitrates back into nitrogen gas (N 2), completing the nitrogen cycle. This process is performed by bacterial species such as Pseudomonas and Paracoccus, under anaerobic conditions. They use the nitrate as an electron acceptor in the place of oxygen during respiration.
The resulting β-nitro alkoxide is protonated by the conjugate acid of the base that originally deprotonated the nitroalkyl structure, giving the respective β-nitro alcohol as product. Henry reaction mechanism. All steps of the Henry reaction are reversible. This is due to the lack of a committed step in the reaction to form product.