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It is the disproportionation of carbon monoxide into carbon dioxide and graphite or its reverse: [1] 2CO ⇌ CO 2 + C Boudouard-Equilibrium at 1 bar calculated with 2 different methods Standard enthalpy of the Boudouard reaction at various temperatures. The Boudouard reaction to form carbon dioxide and carbon is exothermic at all temperatures.
The nucleophilicity of hydroxo ligands is relevant to the role of some M-OH centers in enzymology. For example, in carbonic anhydrase, a zinc hydroxide binds carbon dioxide: [7] L n M−OH + CO 2 ⇌ L n MO−O−CO 2 H. The oxygen evolving complex (OEC) consists of a Mn-Ca-O-OH cluster that is responsible for the biosynthesis of O 2. It is ...
Cobalt(II) hydroxide precipitates as a solid when an alkali metal hydroxide is added to an aqueous solution of Co 2+ salt. [4] For example, Co 2+ + 2 NaOH → Co(OH) 2 + 2 Na + The compound can be prepared by reacting cobalt(II) nitrate in water with a solution of triethylamine N(C 2 H 5) 3 as both the base and a complexing agent. [3]
Cp 2 Fe 2 (CO) 4 was first prepared in 1955 at Harvard by Geoffrey Wilkinson using the same method employed today: the reaction of iron pentacarbonyl and dicyclopentadiene. [7] [8] 2 Fe(CO) 5 + C 10 H 12 → (η 5-C 5 H 5) 2 Fe 2 (CO) 4 + 6 CO + H 2. In this preparation, dicyclopentadiene cracks to give cyclopentadiene, which reacts with Fe(CO ...
Basic copper carbonate is a chemical compound, more properly called copper(II) carbonate hydroxide.It can be classified as a coordination polymer or a salt.It consists of copper(II) bonded to carbonate and hydroxide with formula Cu 2 (CO 3)(OH) 2.
Cobalt(II) thiocyanate is an inorganic compound with the formula Co(SCN) 2. [1] The anhydrous compound is a coordination polymer with a layered structure. The trihydrate, Co(SCN) 2 (H 2 O) 3, is a isothiocyanate complex used in the cobalt thiocyanate test (or Scott test) for detecting cocaine. The test has been responsible for widespread false ...
A chemical equation is the symbolic representation of a chemical reaction in the form of symbols and chemical formulas.The reactant entities are given on the left-hand side and the product entities are on the right-hand side with a plus sign between the entities in both the reactants and the products, and an arrow that points towards the products to show the direction of the reaction. [1]
The compound can be prepared by treating nickel or nickel(II) carbonate with acetic acid: . NiCO 3 + 2 CH 3 CO 2 H + 3 H 2 O → Ni(CH 3 CO 2) 2 ·4 H 2 O + CO 2. The mint-green tetrahydrate has been shown by X-ray crystallography to adopt an octahedral structure, the central nickel centre being coordinated by four water molecules and two acetate ligands. [5]