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The hysteresis of a hydrogel refers to the phenomenon where there is a delay in the deformation and recovery of a hydrogel when it is subjected to mechanical stress and relieved of that stress. This occurs because the polymer chains within a hydrogel rearrange, and the water molecules are displaced, and energy is stored as it deforms in ...
Self-healing hydrogels are a specialized type of polymer hydrogel.A hydrogel is a macromolecular polymer gel constructed of a network of crosslinked polymer chains. Hydrogels are synthesized from hydrophilic monomers by either chain or step growth, along with a functional crosslinker to promote network formation.
SMPs have demonstrated recoverable strains of above 800%. [7] Two important quantities that are used to describe shape-memory effects are the strain recovery rate (R r) and strain fixity rate (R f). The strain recovery rate describes the ability of the material to memorize its permanent shape, while the strain fixity rate describes the ability ...
Experimentally, stress relaxation is determined by step strain experiments, i.e. by applying a sudden one-time strain and measuring the build-up and subsequent relaxation of stress in the material (see figure), in either extensional or shear rheology. a) Applied step strain and b) induced stress as functions of time for a viscoelastic material.
where σ is the applied stress, E is the Young's modulus of the material, and ε is the strain. The spring represents the elastic component of the model's response. [2] Dashpots represent the viscous component of a viscoelastic material. In these elements, the applied stress varies with the time rate of change of the strain:
In metallurgy, recovery is a process by which a metal or alloy's deformed grains can reduce their stored energy by the removal or rearrangement of defects in their crystal structure. These defects, primarily dislocations , are introduced by plastic deformation of the material and act to increase the yield strength of a material.
The strain can be decomposed into a recoverable elastic strain (ε e) and an inelastic strain (ε p). The stress at initial yield is σ 0 . Work hardening , also known as strain hardening , is the process by which a material's load-bearing capacity (strength) increases during plastic (permanent) deformation.
Smart rubber will recover its original mechanical strength within several hours of being split and then subsequently recombined. Residual hydrogen bond donors and acceptors responsible for the self-healing properties of the elastomer remain unpaired until the newly exposed surface comes in contact with another complementary surface, allowing formation of new intermolecular hydrogen bonds.