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The steady state approximation, [1] occasionally called the stationary-state approximation or Bodenstein's quasi-steady state approximation, involves setting the rate of change of a reaction intermediate in a reaction mechanism equal to zero so that the kinetic equations can be simplified by setting the rate of formation of the intermediate equal to the rate of its destruction.
In chemistry, a steady state is a more general situation than dynamic equilibrium. While a dynamic equilibrium occurs when two or more reversible processes occur at the same rate, and such a system can be said to be in a steady state, a system that is in a steady state may not necessarily be in a state of dynamic equilibrium, because some of ...
The method of approach to steady state has also been used to analyze the change in messenger RNA levels when synthesis or degradation changes, and a model has also been reported in which the plateau principle is used to connect the change in messenger RNA synthesis to the expected change in protein synthesis and concentration as a function of time.
Steady-states can be stable or unstable. A steady-state is unstable if a small perturbation in one or more of the concentrations results in the system diverging from its state. In contrast, if a steady-state is stable, any perturbation will relax back to the original steady state. Further details can be found on the page Stability theory.
A complete mechanism must also explain the reason for the reactants and catalyst used, the stereochemistry observed in reactants and products, all products formed and the amount of each. S N 2 reaction mechanism. Note the negatively charged transition state in brackets in which the central carbon atom in question shows five bonds, an unstable ...
The steady-state heat equation for a volume that contains a heat source (the inhomogeneous case), is the Poisson's equation: − k ∇ 2 u = q {\displaystyle -k\nabla ^{2}u=q} where u is the temperature , k is the thermal conductivity and q is the rate of heat generation per unit volume.
In cosmology, the steady-state model or steady state theory is an alternative to the Big Bang theory. In the steady-state model, the density of matter in the expanding universe remains unchanged due to a continuous creation of matter, thus adhering to the perfect cosmological principle , a principle that says that the observable universe is ...
Steady state; Non-reactive system; Analysis. Suppose that the slurry inlet composition (by mass) is 50% solid and 50% water, with a mass flow of 100 kg/min. The tank is assumed to be operating at steady state, and as such accumulation is zero, so input and output must be equal for both the solids and water.