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Electronegativity, symbolized as χ, is the tendency for an atom of a given chemical element to attract shared electrons (or electron density) when forming a chemical bond. [1] An atom's electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the ...
The current theoretical model of the atom involves a dense nucleus surrounded by a probabilistic "cloud" of electrons. Atomic theory is the scientific theory that matter is composed of particles called atoms. The definition of the word "atom" has changed over the years in response to scientific discoveries.
Walsh described in 1947 [10] a relationship between the electronegativity of groups bonded to carbon and the hybridisation of said carbon atom. Finally, in 1961, Bent published a major review of the literature that related molecular structure, central atom hybridisation, and substituent electronegativities [ 2 ] and it is for this work that ...
His contributions to the theory of the chemical bond include the concept of orbital hybridisation and the first accurate scale of electronegativities of the elements. Pauling also worked on the structures of biological molecules, and showed the importance of the alpha helix and beta sheet in protein secondary structure.
In atomic physics and quantum chemistry, Hund's rules refers to a set of rules that German physicist Friedrich Hund formulated around 1925, which are used to determine the term symbol that corresponds to the ground state of a multi-electron atom. The first rule is especially important in chemistry, where it is often referred to simply as Hund's ...
The tendency of an atom in a molecule to attract the shared pair of electrons towards itself is known as electronegativity. It is a dimensionless quantity because it is only a tendency. [16] The most commonly used scale to measure electronegativity was designed by Linus Pauling. The scale has been named the Pauling scale in his honour.
In two papers outlining his "theory of atomicity of the elements" (1857–58), Friedrich August Kekulé was the first to offer a theory of how every atom in an organic molecule was bonded to every other atom. He proposed that carbon atoms were tetravalent, and could bond to themselves to form the carbon skeletons of organic molecules.
Electronegativity is not a uniquely defined property and may depend on the definition. The suggested values are all taken from WebElements as a consistent set. Many of the highly radioactive elements have values that must be predictions or extrapolations, but are unfortunately not marked as such.