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Calcium carbonate precipitates as a solid, leaving ammonium sulfate in the solution. (NH 4) 2 CO 3 + CaSO 4 → (NH 4) 2 SO 4 + CaCO 3. Ammonium sulfate occurs naturally as the rare mineral mascagnite in volcanic fumaroles and due to coal fires on some dumps. [14] Ammonium sulfate is a byproduct in the production of methyl methacrylate. [15]
ABC dry chemical is usually a mix of monoammonium phosphate and ammonium sulfate, the former being the active component. The mix between the two agents is usually 40–60%, 60–40%, or 90–10% depending on local standards worldwide. The USGS uses a similar mixture, called Phos Chek G75F. [2]
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Alkyl sulfates consist of a hydrophobic hydrocarbon chain, a polar sulfate group (containing an anion) and either a cation or amine to neutralize the sulfate group. Examples include: sodium lauryl sulfate (also known as sulfuric acid mono dodecyl ester sodium salt) and related potassium and ammonium salts.
Ammonium sulfate is an inorganic salt with a high solubility that disassociates into ammonium (NH + 4) and sulfate (SO 2− 4) in aqueous solutions. [1] Ammonium sulfate is especially useful as a precipitant because it is highly soluble, stabilizes protein structure, has a relatively low density, is readily available, and is relatively inexpensive.
The ammonium, sodium, and potassium salts adopt very similar structures in the solid state, according to X-ray crystallography. In the ammonium salt, the O-O distance is 1.497 Å. The sulfate groups are tetrahedral , with three short S-O distances near 1.44 Å and one long S-O bond at 1.64 Å.
Ammonium sulfate, [NH 4] 2 SO 4, a side-product insoluble in liquid ammonia, is removed by filtration; the liquid ammonia is evaporated to give the desired product. [4] The net reaction is: 2 NO − 2 + 4 SO 2 + 6 H 2 O + 6 NH 3 → 4 SO 2− 4 + 6 [NH 4] + + 2 NH 2 OH. A base then frees the hydroxylamine from the salt:
Ammonium sulfamate (or ammonium sulphamate) is a white crystalline solid, readily soluble in water. It is commonly used as a broad spectrum herbicide , with additional uses as a compost accelerator, flame retardant and in industrial processes.