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Von Mayer also published a numerical value for mechanical equivalent of heat in 1845 but his experimental method wasn't as convincing. Though a standardised value of 4.1860 J·cal −1 was established in the early 20th century, in the 1920s, it was ultimately realised that the constant is simply the specific heat of water, a quantity that ...
Using these values, Joule was able to determine the mechanical equivalent of heat. Joule estimated a mechanical equivalent of heat to be 819 ft•lbf/Btu (4.41 J/cal). The modern day definitions of heat, work, temperature, and energy all have connection to this experiment. In this arrangement of apparatus, it never happens that the process runs ...
The British imperial units and U.S. customary units for both energy and work include the foot-pound force (1.3558 J), the British thermal unit (BTU) which has various values in the region of 1055 J, the horsepower-hour (2.6845 MJ), and the gasoline gallon equivalent (about 120 MJ). Log-base-10 of the ratios between various measures of energy
The fact that the values obtained both by electrical and purely mechanical means were in agreement to at least two significant digits was, to Joule, compelling evidence of the reality of the convertibility of work into heat. Wherever mechanical force is expended, an exact equivalent of heat is always obtained. —
In 1865, the German physicist Rudolf Clausius stated what he called the "second fundamental theorem in the mechanical theory of heat" in the following form: [75] = where Q is heat, T is temperature and N is the "equivalence-value" of all uncompensated transformations involved in a cyclical process. Later, in 1865, Clausius would come to define ...
In 1845, Joule published a paper entitled The Mechanical Equivalent of Heat, in which he specified a numerical value for the amount of mechanical work required to "produce a unit of heat", based on heat production by friction in the passage of electricity through a resistor and in the rotation of a paddle in a vat of water. [33]
In 1845, Joule published a paper entitled The Mechanical Equivalent of Heat, in which he specified a numerical value for the amount of mechanical work required to "produce a unit of heat", based on heat production by friction in the passage of electricity through a resistor and in the rotation of a paddle in a vat of water. [13]
A key stage in the development of the modern conservation principle was the demonstration of the mechanical equivalent of heat. The caloric theory maintained that heat could neither be created nor destroyed, whereas conservation of energy entails the contrary principle that heat and mechanical work are interchangeable.