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Hydrolysis (/ h aɪ ˈ d r ɒ l ɪ s ɪ s /; from Ancient Greek hydro- 'water' and lysis 'to unbind') is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution , elimination , and solvation reactions in which water is the nucleophile .
Solvation or dissolution is a kinetic process and is quantified by its rate. Solubility quantifies the dynamic equilibrium state achieved when the rate of dissolution equals the rate of precipitation. The consideration of the units makes the distinction clearer. The typical unit for dissolution rate is mol/s.
If the solvation energy is positive, then the solvation process is endergonic; otherwise, it is exergonic. For instance, water warms when treated with CaCl 2 (anhydrous calcium chloride) as a consequence of the large heat of hydration. However, the hexahydrate, CaCl 2 ·6H 2 O cools the water upon dissolution. The latter happens because the ...
In a dissolution process, a solute is changed from a pure phase—solid, liquid, or gas—to a solution phase. If the pure phase of the solute is a solid or gas (presuming the solvent itself is liquid), the process can be seen in two stages: the phase change into a liquid, and the mixing of liquids. The dissolution process is generally ...
Dissociation diagram of phosphoric acid Dissociation in chemistry is a general process in which molecules (or ionic compounds such as salts , or complexes ) separate or split into other things such as atoms, ions, or radicals , usually in a reversible manner.
Solubility equilibrium is a type of dynamic equilibrium that exists when a chemical compound in the solid state is in chemical equilibrium with a solution of that compound. The solid may dissolve unchanged, with dissociation, or with chemical reaction with another constituent of the solution, such as acid or alkali.
The integral heat of dissolution is defined as a process of obtaining a certain amount of solution with a final concentration. The enthalpy change in this process, normalized by the mole number of solute, is evaluated as the molar integral heat of dissolution. Mathematically, the molar integral heat of dissolution is denoted as:
Dissolution (also called simple solution or congruent dissolution) is the process in which a mineral dissolves completely without producing any new solid substance. [24] Rainwater easily dissolves soluble minerals, such as halite or gypsum , but can also dissolve highly resistant minerals such as quartz , given sufficient time. [ 25 ]