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The boiling point of water is the temperature at which the saturated vapor pressure equals the ambient pressure. Water supercooled below its normal freezing point has a higher vapor pressure than that of ice at the same temperature and is, thus, unstable. Calculations of the (saturation) vapor pressure of water are commonly used in meteorology.
Atmospheric pollutant concentrations expressed as mass per unit volume of atmospheric air (e.g., mg/m 3, μg/m 3, etc.) at sea level will decrease with increasing altitude because the atmospheric pressure decreases with increasing altitude. The change of atmospheric pressure with altitude can be obtained from this equation: [2]
The atmospheric pressure is roughly equal to the sum of partial pressures of constituent gases – oxygen, nitrogen, argon, water vapor, carbon dioxide, etc.. In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. [1]
Pressure as a function of the height above the sea level. There are two equations for computing pressure as a function of height. The first equation is applicable to the atmospheric layers in which the temperature is assumed to vary with altitude at a non null lapse rate of : = [,, ()] ′, The second equation is applicable to the atmospheric layers in which the temperature is assumed not to ...
The red line on the chart to the right is the maximum concentration of water vapor expected for a given temperature. The water vapor concentration increases significantly as the temperature rises, approaching 100% (steam, pure water vapor) at 100 °C. However the difference in densities between air and water vapor would still exist (0.598 vs. 1 ...
Up to 99.63 °C (the boiling point of water at 0.1 MPa), at this pressure water exists as a liquid. Above that, it exists as water vapor. Note that the boiling point of 100.0 °C is at a pressure of 0.101325 MPa (1 atm), which is the average atmospheric pressure.
At the normal boiling point of a liquid, the vapor pressure is equal to the standard atmospheric pressure defined as 1 atmosphere, [1] 760 Torr, 101.325 kPa, or 14.69595 psi. For example, at any given temperature, methyl chloride has the highest vapor pressure of any of the liquids in the chart.
Lange's Handbook of Chemistry, McGraw-Hill Professional; Wichterle I., Linek J., "Antoine Vapor Pressure Constants of Pure Compounds" Yaws C. L., Yang H.-C., "To Estimate Vapor Pressure Easily. Antoine Coefficients Relate Vapor Pressure to Temperature for Almost 700 Major Organic Compounds", Hydrocarbon Processing, 68(10), Pages 65–68, 1989