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This 5s 0 configuration, unique in period 5, makes palladium the heaviest element having only one incomplete electron shell, with all shells above it empty. Palladium has the appearance of a soft silver-white metal that resembles platinum. It is the least dense and has the lowest melting point of the platinum group metals.
The first Pd(III) complex characterized by X-ray crystallography was reported in 1987. [3] It was obtained by oxidation of the 1,4,7-trithiacyclononane (ttcn) complex [Pd(ttcn) 2 ] 3+ . X-ray crystallography revealed the expected Jahn–Teller distorted octahedral geometry, in spite of the highly symmetric structure of the ligand .
The platinum-group metals [a] (PGMs) are six noble, precious metallic elements clustered together in the periodic table. These elements are all transition metals in the d-block (groups 8, 9, and 10, periods 5 and 6). [1] The six platinum-group metals are ruthenium, rhodium, palladium, osmium, iridium, and platinum.
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Group 10 elements are observed in oxidation states of +1 to +4. [2] The +2 oxidation state is common for nickel and palladium, while +2 and +4 are common for platinum. Oxidation states of -2 and -1 have also been observed for nickel [3] [4] and platinum, [5] and an oxidation state of +5 has been observed for palladium [6] and platinum. [7]
William Hyde Wollaston FRS (/ ˈ w ʊ l ə s t ən /; 6 August 1766 – 22 December 1828) was an English chemist and physicist who is famous for discovering the chemical elements palladium and rhodium.
Natural palladium (46 Pd) is composed of six stable isotopes, 102 Pd, 104 Pd, 105 Pd, 106 Pd, 108 Pd, and 110 Pd, although 102 Pd and 110 Pd are theoretically unstable. The most stable radioisotopes are 107 Pd with a half-life of 6.5 million years, 103 Pd with a half-life of 17 days, and 100 Pd with a half-life of 3.63 days.
Organopalladium chemistry is a branch of organometallic chemistry that deals with organic palladium compounds and their reactions. Palladium is often used as a catalyst in the reduction of alkenes and alkynes with hydrogen. This process involves the formation of a palladium-carbon covalent bond.