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The phase diagram shows, in pressure–temperature space, the lines of equilibrium or phase boundaries between the three phases of solid, liquid, and gas. The curves on the phase diagram show the points where the free energy (and other derived properties) becomes non-analytic: their derivatives with respect to the coordinates (temperature and ...
Lever rule. In chemistry, the lever rule is a formula used to determine the mole fraction (xi) or the mass fraction (wi) of each phase of a binary equilibrium phase diagram. It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.
Phase rule. In thermodynamics, the phase rule is a general principle governing "pVT" systems, whose thermodynamic states are completely described by the variables pressure (p), volume (V) and temperature (T), in thermodynamic equilibrium. If F is the number of degrees of freedom, C is the number of components and P is the number of phases, then.
Schreinemaker's Analysis is the use of Schreinemaker's Rules to create a phase diagram . After applying Schreinemaker's Rules and creating a phase diagram, the resulting geometric figure will be thermodynamically accurate, although the axes will be undetermined. In order to determine the correct orientation of the geometric figure obtained ...
Supercritical ethane, fluid. [1] In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist. At higher temperatures, the gas ...
Chemistry. In the physical sciences, a phase is a region of material that is chemically uniform, physically distinct, and (often) mechanically separable. In a system consisting of ice and water in a glass jar, the ice cubes are one phase, the water is a second phase, and the humid air is a third phase over the ice and water.
Phase separation. A phase diagram for two isotopes of helium, showing at bottom a range of temperatures and ratios at which they will phase-separate. Phase separation is the creation of two distinct phases from a single homogeneous mixture. [1] The most common type of phase separation is between two immiscible liquids, such as oil and water.
Log-lin pressure-temperature phase diagram of water. The Roman numerals correspond to some ice phases listed below. The phases of ice are all possible states of matter for water as a solid. Variations in pressure and temperature give rise to different phases, which have varying properties and molecular geometries.