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The term "thermal energy" is often used ambiguously in physics and engineering. [1] It can denote several different physical concepts, including: Internal energy: The energy contained within a body of matter or radiation, excluding the potential energy of the whole system, and excluding the kinetic energy of the system moving as a whole.
American Association for the Advancement of Science (1993). Benchmarks for science literacy. New York: Oxford University Press. ISBN 9780195089868. Bruton, Sheila; Ong, Faye (2000). Science content standards for California public schools : kindergarten through grade twelve (PDF). Sacramento, Calif.: Dept. of Education. ISBN 978-0-8011-1496-0
Therefore, only relative free energy values, or changes in free energy, are physically meaningful. The free energy is the portion of any first-law energy that is available to perform thermodynamic work at constant temperature, i.e., work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. [1]
Matter or energy that pass across the boundary so as to effect a change in the internal energy of the system need to be accounted for in the energy balance equation. The volume contained by the walls can be the region surrounding a single atom resonating energy, such as Max Planck defined in 1900; it can be a body of steam or air in a steam ...
The first law of thermodynamics is a formulation of the law of conservation of energy in the context of thermodynamic processes.The law distinguishes two principal forms of energy transfer, heat and thermodynamic work, that modify a thermodynamic system containing a constant amount of matter.
The first and second law of thermodynamics are the most fundamental equations of thermodynamics. They may be combined into what is known as fundamental thermodynamic relation which describes all of the changes of thermodynamic state functions of a system of uniform temperature and pressure.
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