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2 PbCl 2 + 4 RMgBr → R 4 Pb + Pb + 4 MgBrCl 3 PbCl 2 + 6 RMgBr → R 3 Pb-PbR 3 + Pb + 6 MgBrCl [12] These reactions produce derivatives that are more similar to organosilicon compounds, i.e. that Pb(II) tends to disproportionate upon alkylation. PbCl 2 can be used to produce PbO 2 by treating it with sodium hypochlorite (NaClO), forming a ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Thus while carbon tetrachloride is a stable compound, with lead the oxidation state +2 is favored and PbCl 4 quickly becomes PbCl 2. Indeed, the inert pair effect causes lead to favor its +2 oxidation state: Pb atom loses all its outermost p electrons and ends up with a stable, filled s subshell.
A perchlorate is a chemical compound containing the perchlorate ion, ClO − 4, the conjugate base of perchloric acid (ionic perchlorate). As counterions, there can be metal cations , quaternary ammonium cations or other ions, for example, nitronium cation ( NO + 2 ).
Nonpolar bonds generally occur when the difference in electronegativity between the two atoms is less than 0.5; Polar bonds generally occur when the difference in electronegativity between the two atoms is roughly between 0.5 and 2.0; Ionic bonds generally occur when the difference in electronegativity between the two atoms is greater than 2.0
Lead perchlorate trihydrate is produced by the reaction of lead(II) oxide, lead carbonate, or lead nitrate by perchloric acid: . Pb(NO 3) 2 + HClO 4 → Pb(ClO 4) 2 + HNO 3. The excess perchloric acid was removed by first heating the solution to 125 °C, then heating it under moist air at 160 °C to remove the perchloric acid by converting the acid to the dihydrate.
Chlorate is the common name of the ClO − 3 anion, whose chlorine atom is in the +5 oxidation state.The term can also refer to chemical compounds containing this anion, with chlorates being the salts of chloric acid.
For cations that take on multiple charges, the charge is written using Roman numerals in parentheses immediately following the element name. For example, Cu(NO 3) 2 is copper(II) nitrate, because the charge of two nitrate ions (NO − 3) is 2 × −1 = −2, and since the net charge of the ionic compound must be zero, the Cu ion has a 2+ charge ...