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Nickel(II) chloride (or just nickel chloride) is the chemical compound NiCl 2. The anhydrous salt is yellow, but the more familiar hydrate NiCl 2 ·6H 2 O is green. Nickel(II) chloride, in various forms, is the most important source of nickel for chemical synthesis. The nickel chlorides are deliquescent, absorbing moisture from the air to form ...
There are also nickel chloride methoxides with formulae: NiClOMe, Ni 3 Cl 2 (OMe) 4 and Ni 3 Cl(OMe) 5 in which Nickel and oxygen appear to form a cubane-type cluster. [ 68 ] Other alkoxy compounds known for nickel include nickel dipropoxide, nickel di-isopropoxide, nickel tert -amyloxide, and nickel di- tert -hexanoxide. [ 69 ]
Nickel(II) chloride is made by dissolving nickel or its oxide in hydrochloric acid. It is usually found as the green hexahydrate, whose formula is usually written NiCl 2 ·6H 2 O. When dissolved in water, this salt forms the metal aquo complex [Ni(H 2 O) 6] 2+. Dehydration of NiCl 2 ·6H 2 O gives yellow anhydrous NiCl 2. [48] Some ...
Copper(II) sulfate pentahydrate: CuSO 4 ·5H 2 O blue Copper(II) benzoate: Cu(C 7 H 5 O 2) 2: blue Cobalt(II) chloride: CoCl 2: dep blue Cobalt(II) chloride hexahydrate: CoCl 2 ·6H 2 O deep magenta Manganese(II) chloride tetrahydrate: MnCl 2 ·4H 2 O pink Copper(II) chloride dihydrate: CuCl 2 ·2H 2 O blue-green Nickel(II) chloride hexahydrate ...
Hexaamminenickel chloride is the chemical compound with the formula [Ni(NH 3) 6]Cl 2. It is the chloride salt of the metal ammine complex [Ni(NH 3 ) 6 ] 2+ . The cation features six ammonia (called ammines in coordination chemistry) ligands attached to the nickel (II) ion.
Sample of chloropentamminecobalt chloride [CoCl(NH 3) 5]Cl 2, illustrating the vibrant colors typical of transition metal ammine complexes. Zinc(II) forms a colorless tetraammine with the formula [Zn(NH 3) 4] 2+. [13] Like most zinc complexes, it has a tetrahedral structure. Hexaamminenickel is violet, and the
"Nickel dichloride hexahydrate" consists of the chloride complex trans-[NiCl 2 (H 2 O) 4 plus water of crystallization. As indicated in the table below, many hydrates of metal chlorides are molecular complexes. [78] [79] These compounds are often important commercial sources of transition metal chlorides. Several hydrated metal chlorides are ...
Chloride is more easily oxidized than nickel(II). This is a typical halogen displacement reaction, where a halogen plus a less active halide makes the less active halogen and the more active halide. Like some other metal difluorides, NiF 2 crystallizes in the rutile structure, which features octahedral Ni centers and planar fluorides. [ 3 ]