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The phrase "chemical potential" sometimes means "total chemical potential", but that is not universal. [13] In some fields, in particular electrochemistry, semiconductor physics, and solid-state physics, the term "chemical potential" means internal chemical potential, while the term electrochemical potential is used to mean total chemical ...
In electrochemistry, the electrochemical potential of electrons (or any other species) is the total potential, including both the (internal, nonelectrical) chemical potential and the electric potential, and is by definition constant across a device in equilibrium, whereas the chemical potential of electrons is equal to the electrochemical ...
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
Lawrence Stamper Darken has shown that the Gibbs–Duhem equation can be applied to the determination of chemical potentials of components from a multicomponent system from experimental data regarding the chemical potential ¯ of only one component (here component 2) at all compositions.
The number of particles is, like volume and entropy, the displacement variable in a conjugate pair. The generalized force component of this pair is the chemical potential. The chemical potential may be thought of as a force which, when imbalanced, pushes an exchange of particles, either with the surroundings, or between phases inside the system.
A thermodynamic potential (or more accurately, a thermodynamic potential energy) [1] [2] is a scalar quantity used to represent the thermodynamic state of a system. Just as in mechanics , where potential energy is defined as capacity to do work, similarly different potentials have different meanings.
A potential energy surface (PES) or energy landscape describes the energy of a system, especially a collection of atoms, in terms of certain parameters, normally the positions of the atoms. The surface might define the energy as a function of one or more coordinates; if there is only one coordinate, the surface is called a potential energy ...
The Helmholtz free energy is defined as [3], where . F is the Helmholtz free energy (sometimes also called A, particularly in the field of chemistry) (SI: joules, CGS: ergs),; U is the internal energy of the system (SI: joules, CGS: ergs),