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  2. Allyl group - Wikipedia

    en.wikipedia.org/wiki/Allyl_group

    A site adjacent to the unsaturated carbon atom is called the allylic position or allylic site. A group attached at this site is sometimes described as allylic. Thus, CH 2 =CHCH 2 OH "has an allylic hydroxyl group". Allylic C−H bonds are about 15% weaker than the C−H bonds in ordinary sp 3 carbon centers and are thus more reactive.

  3. Vinyl cation - Wikipedia

    en.wikipedia.org/wiki/Vinyl_cation

    1,2-Methyl shifts also occur in vinyl cations, and like 1,2-hydride shifts, they have higher activation barriers compared to their alkyl cation equivalents. In the protonation of alkynes, both 1,2-hydride and 1,2-methyl shifts may take place. The preference depends on the alkyl substituent since it will dictate the resulting allyl cation product.

  4. Steel-toe boot - Wikipedia

    en.wikipedia.org/wiki/Steel-toe_boot

    A steel-toe boot (also known as a safety boot, steel-capped boot, steel toecaps or safety shoe) is a durable boot or shoe that has a protective reinforcement in the toe which protects the foot from falling objects or compression. Safety shoes are effective in keeping the feet of industrial workers safe from sharp and heavy objects while working ...

  5. 17 Rugged Work Boots for Men Designed To Tackle Any and ... - AOL

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  6. Grignard reaction - Wikipedia

    en.wikipedia.org/wiki/Grignard_reaction

    A solution of a carbonyl compound is added to a Grignard reagent. (See gallery) An example of a Grignard reaction (R 2 or R 3 could be hydrogen). The Grignard reaction (French:) is an organometallic chemical reaction in which, according to the classical definition, carbon alkyl, allyl, vinyl, or aryl magnesium halides (Grignard reagent) are added to the carbonyl groups of either an aldehyde or ...

  7. Thigh-high boots - Wikipedia

    en.wikipedia.org/wiki/Thigh-high_boots

    Thigh-high boots, known also as thigh-length boots or simply thigh boots, are boots that extend above the knees to at least mid-thigh. Other terms for this footwear include over-the-knee boots, a name originally used for 15th century riding boots for men. These are sometimes called pirate boots, especially when cuffed. Over-the-knee boots are ...