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PMMA ignites at 460 °C (860 °F) and burns, forming carbon dioxide, water, carbon monoxide, and low-molecular-weight compounds, including formaldehyde. [17] PMMA transmits up to 92% of visible light (3 mm (0.12 in) thickness), [18] and gives a reflection of about 4% from each of its surfaces due to its refractive index (1.4905 at 589.3 nm). [3]
Relative Density 1.19 g/cm3; Rockwell Hardness M 102; Water Absorption 0.2%; Flammability Class 3 (BS 476 pt 7), UL94 HB; Mechanical: Tensile Strength 75 MPa; Flexural Strength 115 MPa; Thermal Properties: Minimum Service Temperature -40°C; Maximum Service Temperature 80°C; Softening Point >110°C; Linear Expansion 7.7×10-5; Optical Properties:
Traditionally, PMMA (acrylic) comprises the core (96% of the cross section in a fiber 1mm in diameter), and fluorinated polymers are the cladding material. Since the late 1990s much higher performance graded-index (GI-POF) fiber based on amorphous fluoropolymer (poly(perfluoro-butenylvinyl ether), CYTOP [1]) has begun to appear in the marketplace.
Poly(methyl acrylate) (PMA) is a family of organic polymers with the formula (CH 2 CHCO 2 CH 3) n.It is a synthetic acrylate polymer derived from methyl acrylate monomer. The polymers are colorless.
The first polymeric form of methacrylic acid was described in 1880 by Engelhorn and Fittig. The use of high purity monomers is required for proper polymerization conditions and therefore it is necessary to remove any inhibitors by extraction (phenolic inhibitors) or via distillation. [ 2 ]
Poly(ethyl methacrylate) (PEMA) is a hydrophobic synthetic acrylate polymer.It has properties similar to the more common PMMA, however it produces less heat during polymerization, has a lower modulus of elasticity and has an overall softer texture. [7]
ASA can be welded to itself or to some other plastics. Ultrasonic welding can be used to join ASA to PVC, ABS, SAN, PMMA, and some others. [4] ASA can be solvent-welded, using e.g. cyclohexane, 1,2-dichloroethane, methylene chloride, or 2-butanone. Such solvents can also join ASA with ABS and SAN.
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