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Two types of molecules having axial chirality: allenes (left) and binaryl atropisomers (right) In chemistry, axial chirality is a special case of chirality in which a molecule contains two pairs of chemical groups in a non-planar arrangement about an axis of chirality so that the molecule is not superposable on its mirror image.
For a chiral molecule with one or more stereocenter, the enantiomer corresponds to the stereoisomer in which every stereocenter has the opposite configuration. An organic compound with only one stereogenic carbon is always chiral. On the other hand, an organic compound with multiple stereogenic carbons is typically, but not always, chiral.
A chiral molecule is a type of molecule that has a non-superposable mirror image. The feature that is most often the cause of chirality in molecules is the presence of an asymmetric carbon atom. [16] [17] The term "chiral" in general is used to describe the object that is non-superposable on its mirror image. [18]
In organic chemistry, allenes are organic compounds in which one carbon atom has double bonds with each of its two adjacent carbon atoms (R 2 C=C=CR 2, where R is H or some organyl group). [1] Allenes are classified as cumulated dienes. The parent compound of this class is propadiene (H 2 C=C=CH 2), which is itself also called allene.
Chirality with hands and two enantiomers of a generic amino acid The direction of current flow and induced magnetic flux follow a "handness" relationship. The term chiral / ˈ k aɪ r əl / describes an object, especially a molecule, which has or produces a non-superposable mirror image of itself.
Examples are present in tetrahedral silicon tetrafluoride, with three S 4 axes, and the staggered conformation of ethane with one S 6 axis. An S 1 axis corresponds to a mirror plane σ and an S 2 axis is an inversion center i. A molecule which has no S n axis for any value of n is a chiral molecule.
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Homochirality is a uniformity of chirality, or handedness.Objects are chiral when they cannot be superposed on their mirror images. For example, the left and right hands of a human are approximately mirror images of each other but are not their own mirror images, so they are chiral.