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The first line in the spectrum of the Lyman series was discovered in 1906 by physicist Theodore Lyman IV, who was studying the ultraviolet spectrum of electrically excited hydrogen gas. The rest of the lines of the spectrum (all in the ultraviolet) were discovered by Lyman from 1906-1914.
1625 – First description of hydrogen by Johann Baptista van Helmont. First to use the word "gas". 1650 – Turquet de Mayerne obtains a gas or "inflammable air" by the action of dilute sulphuric acid on iron. 1662 – Boyle's law (gas law relating pressure and volume). 1670 – Robert Boyle produces hydrogen by reacting metals with acid.
The spectral series of hydrogen, on a logarithmic scale. The emission spectrum of atomic hydrogen has been divided into a number of spectral series, with wavelengths given by the Rydberg formula. These observed spectral lines are due to the electron making transitions between two energy levels in an atom.
Lyman-alpha, typically denoted by Ly-α, is a spectral line of hydrogen (or, more generally, of any one-electron atom) in the Lyman series. It is emitted when the atomic electron transitions from an n = 2 orbital to the ground state ( n = 1), where n is the principal quantum number .
As with many subsequent spectroscopy experiments, Newton's sources of white light included flames and stars, including the Sun. Subsequent studies of the nature of light include those of Hooke, [7] Huygens, [8] Young. [9] [10] Subsequent experiments with prisms provided the first indications that spectra were associated uniquely with chemical ...
The Lyman alpha line is the n=2 to n=1 transition of neutral hydrogen, and can be produced copiously by galaxies with young stars. [14] Moreover, Lyman alpha photons interact strongly with neutral hydrogen in intergalactic gas through resonant scattering, wherein neutral atoms in the ground (n=1) state absorb Lyman alpha photons and almost ...
A hydrogen molecule can absorb a far-ultraviolet photon (11.2 eV < energy of the photon < 13.6 eV) and make a transition from the ground electronic state X to excited state B (Lyman) or C (Werner). Radiative decay occurs rapidly. 10–15% of the decays occur into the vibrational continuum. This means that the hydrogen molecule has dissociated.
The energy of the Lyman-alpha transition is 10.2 eV—this energy is approximately two million times greater than the hydrogen line, and is produced by astrophysical sources such as stars and quasars. Neutral hydrogen absorbs Lyman-alpha photons, and then re-emits Lyman-alpha photons, and may enter either of the two spin states.