Search results
Results From The WOW.Com Content Network
Partition coefficients can be measured experimentally in various ways (by shake-flask, HPLC, etc.) or estimated by calculation based on a variety of methods (fragment-based, atom-based, etc.). If a substance is present as several chemical species in the partition system due to association or dissociation, each species is assigned its own K ow ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. [1] In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures ...
Sodium hydroxide can form several hydrates NaOH·nH 2 O, which result in a complex solubility diagram that was described in detail by Spencer Umfreville Pickering in 1893. [18] The known hydrates and the approximate ranges of temperature and concentration (mass percent of NaOH) of their saturated water solutions are: [ 13 ]
Solubility products are often expressed in logarithmic form. Thus, for calcium sulfate, with K sp = 4.93 × 10 −5 mol 2 dm −6, log K sp = −4.32. The smaller the value of K sp, or the more negative the log value, the lower the solubility. Some salts are not fully dissociated in solution.
Due to the increase in concentration of H + ions from the added HCl, the equilibrium of the dissociation of H 2 S shifts to the left and keeps the value of K a constant. Thus the dissociation of H 2 S decreases, the concentration of un-ionized H 2 S increases, and as a result, the concentration of sulfide ions decreases.
‡ Dissolved CO 2 volume per volume H 2 O: grams CO 2 per 100 ml H 2 O: 0 °C: 1.713: 0.3346 1 °C: ... Carbon dioxide liquid/vapor equilibrium thermodynamic data ...
The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.