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Arsenate readily reacts with metals to form arsenate metal compounds. [2] [3] Arsenate is a moderate oxidizer and an electron acceptor, with an electrode potential of +0.56 V for its reduction to arsenite. [4] Due to arsenic having the same valency and similar atomic radius to phosphorus, arsenate shares similar geometry and reactivity with ...
Arsenate (+5 oxidation state) is the dominant form of arsenic in surface water, while arsenite (+3 oxidation state) is the dominant form in hypoxic to anoxic environments. Arsenite is more soluble and mobile than arsenate. Many species of bacteria can transform arsenite to arsenate in anoxic conditions by using arsenite as an electron donor. [189]
Arsenic trioxide powder.. Compounds of arsenic resemble in some respects those of phosphorus which occupies the same group (column) of the periodic table.The most common oxidation states for arsenic are: −3 in the arsenides, which are alloy-like intermetallic compounds, +3 in the arsenites, and +5 in the arsenates and most organoarsenic compounds.
An arsenate arsenite is a chemical compound or salt that contains arsenate and arsenite anions (AsO 3 3-and AsO 4 3-). These are mixed anion compounds or mixed valence compounds. Some have third anions. Most known substances are minerals, but a few artificial arsenate arsenite compounds have been made. Many of the minerals are in the Hematolite ...
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO 4) 3− anion group and, more rarely, other arsenates with anions like AsO 3 (OH) 2− (also written HAsO 4 2−) (example: pharmacolite Ca(AsO 3 OH). 2H 2 O) or (very rarely) [AsO 2 (OH) 2] − (example: andyrobertsite). Arsenite minerals are much ...
Arthurite is a mineral composed of divalent copper and iron ions in combination with trivalent arsenate, phosphate and sulfate ions with hydrogen and oxygen. [2] Initially discovered by Sir Arthur Russell in 1954 at Hingston Down Consols mine in Calstock, Cornwall, England, [3] arthurite is formed as a resultant mineral in the oxidation region of some copper deposits by the variation of ...
Disodium hydrogen arsenate is the inorganic compound with the formula Na 2 HAsO 4. 7H 2 O. The compound consists of a salt and seven molecules of water of crystallization although for simplicity the formula usually omits the water component. The other sodium arsenates are NaH 2 AsO 4 and Na 3 AsO 4, the latter being called sodium arsenate ...
Arsenic (III) binding sites usually use thiol groups of cysteine residues. The catalysis involves thiolates of Cys72, Cys174, and Cys224. In an SN2 reaction, the positive charge on the SAM sulfur atom pulls the bonding electron from the carbon of the methyl group, which interacts with the arsenic lone pair to form an As−C bond, leaving SAH. [31]