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Phosphogypsum (PG) is the calcium sulfate hydrate formed as a by-product of the production of fertilizer, particularly phosphoric acid, from phosphate rock. It is mainly composed of gypsum (CaSO 4 ·2H 2 O).
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO 4 and related hydrates. In the form of γ- anhydrite (the anhydrous form), it is used as a desiccant . One particular hydrate is better known as plaster of Paris , and another occurs naturally as the mineral gypsum .
Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO 4 ·2H 2 O. [4] It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk chalk.
A gypsum block is made of gypsum plaster and water. The manufacturing process [1] is automated at production plants where raw gypsum (CaSO 4 ·2H 2 O) is ground and dried, then heated to remove three-quarters of the bound water and thus transformed into calcium sulfate hemihydrate (CaSO 4 ·½H 2 O), also known as gypsum plaster, stucco, calcined gypsum or plaster of Paris.
Regulation and expression of the majority of sulfate transporters are controlled by the sulfur nutritional status of the plants. [8] Upon sulfate deprivation, the rapid decrease in root sulfate is regularly accompanied by a strongly enhanced expression of most sulfate transporter genes (up to 100-fold), accompanied by a substantially enhanced ...
The oxidation of water is catalyzed in photosystem II by a redox-active structure that contains four manganese ions and a calcium ion; this oxygen-evolving complex binds two water molecules and contains the four oxidizing equivalents that are used to drive the water-oxidizing reaction (Kok's S-state diagrams).
About 2.2:1 is the ratio (by weight) for compounding sulfur and quicklime; this makes the highest proportion of calcium pentasulfide. If calcium hydroxide (builders or hydrated lime) is used, an increase by 1/3 or more (to 115 g/L or more) might be used with the 192 g/L of sulfur. If the quicklime is 85%, 90%, or 95% pure, use 101 g/L, 96 g/L ...
An example of the temperature dependence of solubility is shown in the figure. Calcium sulfate is a common precipitation foulant of heating surfaces due to its retrograde solubility. Precipitation fouling can also occur in the absence of heating or vaporization. For example, calcium sulfate decreases its solubility with decreasing pressure.