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To determine whether a polymer will undergo surface or bulk erosion, the degradation rate of the polymer in water (how fast the polymer reacts to water) and the rate of diffusion of water penetrating through the material must be considered. If the degradation process is faster than the diffusion process, surface erosion will occur since the ...
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the Van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
where A is the reactant and S is an adsorption site on the surface and the respective rate constants for the adsorption, desorption and reaction are k 1, k −1 and k 2, then the global reaction rate is: = = where: r is the rate, mol·m −2 ·s −1
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
In chemistry, the rate equation (also known as the rate law or empirical differential rate equation) is an empirical differential mathematical expression for the reaction rate of a given reaction in terms of concentrations of chemical species and constant parameters (normally rate coefficients and partial orders of reaction) only. [1]
The equation follows from the transition state theory, also known as activated-complex theory. If one assumes a constant enthalpy of activation and constant entropy of activation, the Eyring equation is similar to the empirical Arrhenius equation, despite the Arrhenius equation being empirical and the Eyring equation based on statistical ...
Wagner derived that when attachment and detachment of molecules is slower than diffusion, then the growth rate becomes = where k s is the reaction rate constant of attachment with units of length per time. Since the average radius is usually something that can be measured in experiments, it is fairly easy to tell if a system is obeying the slow ...
L. M. Kachanov [5] and Y. N. Rabotnov [6] suggested the following evolution equations for the creep strain ε and a lumped damage state variable ω: ˙ = ˙ ˙ = ˙ where ˙ is the creep strain rate, ˙ is the creep-rate multiplier, is the applied stress, is the creep stress exponent of the material of interest, ˙ is the rate of damage accumulation, ˙ is the damage-rate multiplier, and is ...