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Some of the hydrogen sulfide will react with metal ions in the water or solid to produce iron or metal sulfides, which are not water-soluble. These metal sulfides, such as iron(II) sulfide, are often black or brown, leading to the color of sludge. Pyrrhotite is a waste product of the Desulfovibrio bacteria, a sulfate reducing bacteria.
Iron sulfide or Iron sulphide can refer to range of chemical compounds composed of iron and sulfur. Minerals. By increasing order of stability: Iron(II) sulfide, FeS;
The mineral pyrite (/ ˈ p aɪ r aɪ t / PY-ryte), [6] or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S 2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral .
Iron(II,III) sulfide is a blue-black (sometimes pinkish [citation needed]) chemical compound of iron and sulfur with formula Fe 3 S 4 or FeS·Fe 2 S 3, which is much similar to iron(II,III) oxide. It occurs naturally as the sulfide mineral greigite and is magnetic. It is a bio-mineral produced by and found in magnetotactic bacteria.
The mineral marcasite, sometimes called "white iron pyrite", is iron sulfide (FeS 2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both structures contain the disulfide S 2 2− ion, having a short bonding distance between the sulfur atoms.
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Pyrrhotite requires both iron and sulfur to form. [6] Iron is the fourth most abundant element in the Earth's continental crust (average abundance of 5.63 % or 56,300 mg/kg in the crust), [21] and so the majority of rocks have sufficient iron abundance to form pyrrhotite. [6]
Iron sulfate compounds (e.g., jarosite, schwertmannite, gypsum, and epsomite) H-Clay (hydrogen clay, with a large fraction of adsorbed H + ions, a stable mineral, but poor in nutrients) The iron can be present in bivalent and trivalent forms (Fe 2+, the ferrous ion, and Fe 3+, the ferric ion respectively).