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  2. Trigonal bipyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_bipyramidal...

    In chemistry, a trigonal bipyramid formation is a molecular geometry with one atom at the center and 5 more atoms at the corners of a triangular bipyramid. [1] This is one geometry for which the bond angles surrounding the central atom are not identical (see also pentagonal bipyramid), because there is no geometrical arrangement with five terminal atoms in equivalent positions.

  3. Seesaw molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Seesaw_molecular_geometry

    The seesaw geometry occurs when a molecule has a steric number of 5, with the central atom being bonded to 4 other atoms and 1 lone pair (AX 4 E 1 in AXE notation). An atom bonded to 5 other atoms (and no lone pairs) forms a trigonal bipyramid with two axial and three equatorial positions, but in the seesaw geometry one of the atoms is replaced ...

  4. Triangular bipyramid - Wikipedia

    en.wikipedia.org/wiki/Triangular_bipyramid

    A triangular bipyramid is a known solution in the case of five electrons, placing vertices of a triangular bipyramid within a sphere. [18] This solution is aided by a mathematically rigorous computer. [19] A chemical compound's trigonal bipyramidal molecular geometry may be described as the atom cluster of a triangular bipyramid

  5. Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Molecular_geometry

    For example, sulfur hexafluoride (SF 6) is an octahedral molecule. Trigonal pyramidal: A trigonal pyramidal molecule has a pyramid-like shape with a triangular base. Unlike the linear and trigonal planar shapes but similar to the tetrahedral orientation, pyramidal shapes require three dimensions in order to fully separate the electrons.

  6. Berry mechanism - Wikipedia

    en.wikipedia.org/wiki/Berry_mechanism

    Trigonal bipyramidal molecular shape ax = axial ligands (on unique axis) eq = equatorial ligand (in plane perpendicular to unique axis). The Berry mechanism, or Berry pseudorotation mechanism, is a type of vibration causing molecules of certain geometries to isomerize by exchanging the two axial ligands (see the figure) for two of the equatorial ones.

  7. Trigonal pyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_pyramidal...

    In chemistry, a trigonal pyramid is a molecular geometry with one atom at the apex and three atoms at the corners of a trigonal base, resembling a tetrahedron (not to be confused with the tetrahedral geometry). When all three atoms at the corners are identical, the molecule belongs to point group C 3v.

  8. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    On the other hand, there are only three outer atoms. This is referred to as an AX 3 E type molecule because the lone pair is represented by an E. [1]: 410–417 By definition, the molecular shape or geometry describes the geometric arrangement of the atomic nuclei only, which is trigonal-pyramidal for NH 3. [1]: 410–417

  9. T-shaped molecular geometry - Wikipedia

    en.wikipedia.org/wiki/T-shaped_molecular_geometry

    The T-shaped geometry is related to the trigonal bipyramidal molecular geometry for AX 5 molecules with three equatorial and two axial ligands. In an AX 3 E 2 molecule, the two lone pairs occupy two equatorial positions, and the three ligand atoms occupy the two axial positions as well as one equatorial position. The three atoms bond at 90 ...