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Violet phosphorus (right) by a sample of red phosphorus (left) Hitorff's phosphorus structure. Monoclinic phosphorus, violet phosphorus, or Hittorf's metallic phosphorus is a crystalline form of the amorphous red phosphorus. [15] [16] In 1865, Johann Wilhelm Hittorf heated red phosphorus in a sealed tube at 530 °C. The upper part of the tube ...
The characteristic properties of elemental metals and nonmetals are quite distinct, as shown in the table below. Metalloids, straddling the metal-nonmetal border , are mostly distinct from either, but in a few properties resemble one or the other, as shown in the shading of the metalloid column below and summarized in the small table at the top ...
Diamond and graphite are two allotropes of carbon: pure forms of the same element that differ in crystalline structure.. Allotropy or allotropism (from Ancient Greek ἄλλος (allos) 'other' and τρόπος (tropos) 'manner, form') is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements.
Phosphorus is classified as a pnictogen, together with nitrogen, arsenic, antimony, bismuth, and moscovium. Phosphorus is an element essential to sustaining life largely through phosphates, compounds containing the phosphate ion, PO 4 3−. Phosphates are a component of DNA, RNA, ATP, and phospholipids, complex compounds fundamental to cells.
The general formula of a phosphoric acid is H n−2x+2 P n O 3n−x+1, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure; that is, the minimum number of bonds that would have to be broken to eliminate all cycles.
Bettelheim et al. The nonmetals are distinguished based on the molecular structures of their most thermodynamically stable forms in ambient conditions. [5] Polyatomic nonmetals form structures or molecules in which each atom has two or three nearest neighbours (carbon: C x; phosphorus: P 4; sulfur: S 8; selenium: Se x); diatomic nonmetals form molecules in which each atom has one nearest ...
In comparison to nitrogen, phosphorus usually forms weak hydrogen bonds, and prefers to form complexes with metals having high electronegativities, large cationic radii, and often low charges (usually +1 or +2. Phosphorus is a poor oxidising agent (P 4 + 3e − → PH 3 – = −0.046 V at pH 0 for the white form, −0.088 V for the red). Its ...
Organophosphorus chemistry is the scientific study of the synthesis and properties of organophosphorus compounds, which are organic compounds containing phosphorus. [1] They are used primarily in pest control as an alternative to chlorinated hydrocarbons that persist in the environment.