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As potassium permanganate is titrated, the solution becomes a light shade of purple, which darkens as excess of the titrant is added to the solution. In a related way, it is used as a reagent to determine the Kappa number of wood pulp. For the standardization of KMnO 4 solutions, reduction by oxalic acid is often used. [47]
Oxalic acid is used by some beekeepers as a miticide against the parasitic varroa mite. [52] Dilute solutions (0.05–0.15 M) of oxalic acid can be used to remove iron from clays such as kaolinite to produce light-colored ceramics. [53] Oxalic acid can be used to clean minerals like many other acids. Two such examples are quartz crystals and ...
It is the sodium salt of oxalic acid. It contains sodium cations Na + and oxalate anions C 2 O 2− 4. It is a white, crystalline, odorless solid, that decomposes above 290 °C. [2] Sodium oxalate can act as a reducing agent, and it may be used as a primary standard for standardizing potassium permanganate (KMnO 4) solutions.
A permanganate can oxidize an amine to a nitro compound, [7] [8] a secondary alcohol to a ketone, [9] a primary alcohol or aldehyde to a carboxylic acid, [10] [11] a terminal alkene to a carboxylic acid, [12] oxalic acid to carbon dioxide, [13] and an alkene to a diol. [14] This list is not exhaustive. In alkene oxidations one intermediate is a ...
Potassium manganate is the inorganic compound with the formula K 2 MnO 4. This green-colored salt is an intermediate in the industrial synthesis of potassium permanganate (KMnO 4), a common chemical. [1] Occasionally, potassium manganate and potassium permanganate are confused, but each compound's properties are distinct.
Potassium hydrogenoxalate is a salt with formula KHC 2 O 4 or K + ·HO 2 C-CO 2 −.It is one of the most common salts of the hydrogenoxalate anion, and can be obtained by reacting potassium hydroxide with oxalic acid in 1:1 mole ratio.
Depending on the conditions in which the titration is performed, the manganese is reduced from an oxidation of +7 to +2, +4, or +6. In most cases, permanganometry is performed in a very acidic solution in which the following electrochemical reaction occurs: [3]
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75