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Sodium peroxide is an inorganic compound with the formula Na 2 O 2.This yellowish solid is the product of sodium ignited in excess oxygen. [3] It is a strong base. This metal peroxide exists in several hydrates and peroxyhydrates including Na 2 O 2 ·2H 2 O 2 ·4H 2 O, Na 2 O 2 ·2H 2 O, Na 2 O 2 ·2H 2 O 2, and Na 2 O 2 ·8H 2 O. [4] The octahydrate, which is simple to prepare, is white, in ...
Unit cell of sodium peroxide Na 2 O 2. The sodium ions are violet and the peroxide ions in red. In chemistry, metal peroxides are metal-containing compounds with ionically- or covalently-bonded peroxide (O 2− 2) groups. This large family of compounds can be divided into ionic and covalent peroxide.
Sodium peroxide (Na 2 O 2) is used to oxidize the sample that becomes soluble in a diluted acid solution. This method allows complete dissolution of numerous refractory compounds like chromite , magnetite , ilmenite , rutile , and even silicon , carbides , alloys , noble metals and materials with high sulfide contents.
Typically aqueous sodium hydroxide solutions are used. [1] [2] It is an important type of alkaline hydrolysis. When the carboxylate is long chain, its salt is called a soap. The saponification of ethyl acetate gives sodium acetate and ethanol: C 2 H 5 O 2 CCH 3 + NaOH → C 2 H 5 OH + NaO 2 CCH 3
Sodium persulfate is the inorganic compound with the formula Na 2 S 2 O 8. It is the sodium salt of peroxydisulfuric acid , H 2 S 2 O 8 , an oxidizing agent . It is a white solid that dissolves in water.
Many industrial peroxides are produced using hydrogen peroxide. Reactions with aldehydes and ketones yield a series of compounds depending on conditions. Specific reactions include addition of hydrogen peroxide across the C=O double bond: R 2 C=O + H 2 O 2 → R 2 C(OH)OOH. In some cases, these hydroperoxides convert to give cyclic diperoxides:
Hydroxyl radicals are also produced during UV-light dissociation of H 2 O 2 (suggested in 1879) and likely in Fenton chemistry, where trace amounts of reduced transition metals catalyze peroxide-mediated oxidations of organic compounds. In organic synthesis hydroxyl radicals are most commonly generated by photolysis of 1-Hydroxy-2(1H ...
Diacyl peroxides are typically prepared by treating hydrogen peroxide with acid chlorides or acid anhydrides in the presence of base: [1] H 2 O 2 + 2 RCOCl → (RCO 2) 2 + 2 HCl H 2 O 2 + (RCO) 2 O → (RCO 2) 2 + H 2 O. The reaction competes with hydrolysis of the acylating agent but the hydroperoxide anion is a superior nucleophile relative ...