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Fritz Haber, 1918. The Haber process, [1] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [2] [3] It converts atmospheric nitrogen (N 2) to ammonia (NH 3) by a reaction with hydrogen (H 2) using finely divided iron metal as a catalyst:
Forming gas is a mixture of hydrogen (mole fraction varies) [1] and nitrogen. It is sometimes called a "dissociated ammonia atmosphere" due to the reaction which generates it: 2 NH 3 → 3 H 2 + N 2. It can also be manufactured by thermal cracking of ammonia, in an ammonia cracker or forming gas generator. [2]
The amount of mass that can be lifted by hydrogen in air per unit volume at sea level, equal to the density difference between hydrogen and air, is: (1.292 - 0.090) kg/m 3 = 1.202 kg/m 3. and the buoyant force for one m 3 of hydrogen in air at sea level is: 1 m 3 × 1.202 kg/m 3 × 9.8 N/kg= 11.8 N
The Ostwald process begins with burning ammonia.Ammonia burns in oxygen at temperature about 900 °C (1,650 °F) and pressure up to 8 standard atmospheres (810 kPa) [4] in the presence of a catalyst such as platinum gauze, alloyed with 10% rhodium to increase its strength and nitric oxide yield, platinum metal on fused silica wool, copper or nickel to form nitric oxide (nitrogen(II) oxide) and ...
The hydrogen in ammonia is susceptible to replacement by a myriad substituents. Ammonia gas reacts with metallic sodium to give sodamide, NaNH 2. [38] With chlorine, monochloramine is formed. Pentavalent ammonia is known as λ 5-amine, nitrogen pentahydride decomposes spontaneously into trivalent ammonia (λ 3-amine) and hydrogen gas at normal ...
The United States produces 9–10 million tons of hydrogen per year, mostly with steam reforming of natural gas. [13] The worldwide ammonia production, using hydrogen derived from steam reforming, was 144 million tonnes in 2018. [14] The energy consumption has been reduced from 100 GJ/tonne of ammonia in 1920 to 27 GJ by 2019. [15]
The Haber process produces ammonia (NH 3) from molecular nitrogen (N 2) and hydrogen (H 2), the latter usually but not necessarily produced by steam reforming methane (CH 4) gas in current practice. The ammonia from the Haber process is then converted into nitric acid (HNO 3) in the Ostwald process. [7]
The liquid nitrogen wash has two principle functions: [1] Removal of impurities such as carbon monoxide, argon and methane from the crude hydrogen gas; Addition of the required stoichiometric amount of nitrogen to the hydrogen stream to achieve the correct ammonia synthesis gas ratio of hydrogen to nitrogen of 3 : 1