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In organic chemistry, an electrocyclic reaction can either be classified as conrotatory or disrotatory based on the rotation at each end of the molecule. In conrotatory mode, both atomic orbitals of the end groups turn in the same direction (such as both atomic orbitals rotating clockwise or counter-clockwise). In disrotatory mode, the atomic ...
In chemistry, rotamers are chemical species that differ from one another primarily due to rotations about one or more single bonds. Various arrangements of atoms in a molecule that differ by rotation about single bonds can also be referred to as different conformations. Conformers/rotamers differ little in their energies, so they are almost ...
In organic chemistry, an electrocyclic reaction is a type of pericyclic, rearrangement reaction where the net result is one pi bond being converted into one sigma bond or vice versa. [1] These reactions are usually categorized by the following criteria: Reactions can be either photochemical or thermal.
In organic chemistry, cheletropic reactions, also known as chelotropic reactions, [2] are a type of pericyclic reaction (a chemical reaction that involves a transition state with a cyclic array of atoms and an associated cyclic array of interacting orbitals). [1] Specifically, cheletropic reactions are a subclass of cycloadditions.
(To some extent rotation influences the geometry via Coriolis forces and centrifugal distortion, but this is negligible for the present discussion.) In addition to translation and rotation, a third type of motion is molecular vibration , which corresponds to internal motions of the atoms such as bond stretching and bond angle variation.
In physics and chemistry, a degree of freedom is an independent physical parameter in the chosen parameterization of a physical system.More formally, given a parameterization of a physical system, the number of degrees of freedom is the smallest number of parameters whose values need to be known in order to always be possible to determine the values of all parameters in the chosen ...
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