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Crystal structure of CH 3 NH 3 PbX 3 perovskites (X=I, Br and/or Cl). The methylammonium cation (CH 3 NH 3 +) is surrounded by PbX 6 octahedra. [13]The name "perovskite solar cell" is derived from the ABX 3 crystal structure of the absorber materials, referred to as perovskite structure, where A and B are cations and X is an anion.
A perovskite is a crystalline material of formula ABX 3 with a crystal structure similar to that of the mineral perovskite, this latter consisting of calcium titanium oxide (CaTiO 3). [2] The mineral was first discovered in the Ural mountains of Russia by Gustav Rose in 1839 and named after Russian mineralogist L. A. Perovski (1792–1856).
The main obstacle to viable tin perovskite solar cells is the instability of tin's oxidation state Sn 2+, which is easily oxidized to the stabler Sn 4+. [10] In solar cell research, this process is called self-doping, [11] because the Sn 4+ acts as a p-dopant and reduces solar cell efficiency.
Methylammonium lead halides (MALHs) are solid compounds with perovskite structure and a chemical formula of [CH 3 NH 3] + Pb 2+ (X −) 3, where X = Cl, Br or I. They have potential applications in solar cells, [2] lasers, light-emitting diodes, photodetectors, radiation detectors, [3] [4] scintillator, [5] magneto-optical data storage [6] and ...
Perovskite (pronunciation: / p ə ˈ r ɒ v s k aɪ t /) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula Ca Ti O 3).Its name is also applied to the class of compounds which have the same type of crystal structure as CaTiO 3, known as the perovskite structure, which has a general chemical formula A 2+ B 4+ (X 2−) 3. [6]
Classification of perovskite and other ABO3-type compounds: Author: Roth, R.S. Software used: Adobe Acrobat 9.0: Conversion program: Adobe Acrobat 9.13 Paper Capture Plug-in: Encrypted: no: Page size: 537.48 x 720 pts; 537 x 720 pts; 536.04 x 720 pts; 536.52 x 720 pts; Version of PDF format: 1.4
This occurs as a result of the distortion of the perovskite structure and the tilting of octahedra due to the size of the A-cation. Cs, which yields a Goldschmidt tolerance factor of less than one, results in a distorted, orthorhombic structure at room temperature. This results in reduced orbital overlap between the halide and lead atoms and ...
Perovskite solar cells are also forecast to be extremely cheap to scale up, making them a very attractive option for commercialisation. So far most types of perovskite solar cells have not reached sufficient operational stability to be commercialised, although many research groups are investigating ways to solve this. [99]