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An example is the [1,3]-hydride shift, in which the interacting frontier orbitals are the allyl free radical and the hydrogen 1s orbitals. The suprafacial shift is symmetry-forbidden because orbitals with opposite algebraic signs overlap. The symmetry allowed antarafacial shift would require a strained transition state and is also unlikely. In ...
The presence of an organic haze in Earth's Archean atmosphere was first suggested in 1983 and could have been responsible for an anti-greenhouse effect. [ 14 ] [ 15 ] This hypothesis stems from attempts at resolving the faint young Sun paradox , where a reduced solar output in the past must be reconciled with the existence of liquid water on ...
In web search engines, organic search results are the query results which are calculated strictly algorithmically, and not affected by advertiser payments. They are distinguished from various kinds of sponsored results, whether they are explicit pay per click advertisements, shopping results, or other results where the search engine is paid either for showing the result, or for clicks on the ...
In organic chemistry, syn-and anti-addition are different ways in which substituent molecules can be added to an alkene (R 2 C=CR 2) or alkyne (RC≡CR).The concepts of syn and anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction.
Anoxia is further influenced by biochemical oxygen demand (BOD), which is the amount of oxygen used by marine organisms in the process of breaking down organic matter. BOD is influenced by the type of organisms present, the pH of the water, temperature, and the type of organic matter present in the area.
Organoclay is an organically modified phyllosilicate, derived from a naturally occurring clay mineral. By exchanging the original interlayer cations for organocations (typically quaternary alkylammonium ions) an organophilic surface is generated, consisting of covalently linked organic moieties. The lamellar structure remains analogous to the ...
Organic architecture is a philosophy of architecture which promotes harmony between human habitation and the natural world. This is achieved through design approaches that aim to be sympathetic and well-integrated with a site, so buildings, furnishings, and surroundings become part of a unified, interrelated composition.
Released from alpha cells in the pancreas either when starving or when the body needs to generate additional energy; it stimulates the breakdown of glycogen in the liver to increase blood glucose levels; its effect is the opposite of insulin; glucagon and insulin are a part of a negative-feedback system that stabilizes blood glucose levels ...