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Relation between pH and pOH. Red represents the acidic region. Blue represents the basic region. pOH is sometimes used as a measure of the concentration of hydroxide ions, OH −. By definition, pOH is the negative logarithm (to the base 10) of the hydroxide ion concentration (mol/L). pOH values can be derived from pH measurements and vice-versa.
In and of themselves, pH indicators are usually weak acids or weak bases. The general reaction scheme of acidic pH indicators in aqueous solutions can be formulated as: HInd (aq) + H 2 O (l) ⇌ H 3 O + (aq) + Ind − (aq) where, "HInd" is the acidic form and "Ind −" is the conjugate base of the indicator. Vice versa for basic pH indicators ...
Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
Portable, or field pH meters, are handheld pH meters that are used to take the pH of a sample in a field or production site. [19] In-line or in situ pH meters, also called pH analyzers, are used to measure pH continuously in a process, and can stand-alone, or be connected to a higher level information system for process control. [20]
For obtaining the values of the reduction potential at pH = 7 for the redox reactions relevant for biological systems, the same kind of conversion exercise is done using the corresponding Nernst equation expressed as a function of pH. The conversion is simple, but care must be taken not to inadvertently mix reduction potential converted at pH ...
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Phosphinous acids are usually organophosphorus compounds with the formula R 2 POH. They are pyramidal in structure. Phosphorus is in the oxidation state III. Most phosphinous acids rapidly convert to the corresponding phosphine oxide, which are tetrahedral and are assigned oxidation state V.