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An infrared spectroscopy correlation table (or table of infrared absorption frequencies) is a list of absorption peaks and frequencies, typically reported in wavenumber, for common types of molecular bonds and functional groups.
The method or technique of infrared spectroscopy is conducted with an instrument called an infrared spectrometer (or spectrophotometer) which produces an infrared spectrum. An IR spectrum can be visualized in a graph of infrared light absorbance (or transmittance ) on the vertical axis vs. frequency , wavenumber or wavelength on the horizontal ...
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
The gaps between the bands define the infrared window in the Earth's atmosphere. [17] The infrared spectrum of liquid water is dominated by the intense absorption due to the fundamental O-H stretching vibrations. Because of the high intensity, very short path lengths, usually less than 50 μm, are needed to record the spectra of aqueous solutions.
Example of a linear molecule. N atoms in a molecule have 3N degrees of freedom which constitute translations, rotations, and vibrations.For non-linear molecules, there are 3 degrees of freedom for translational (motion along the x, y, and z directions) and 3 degrees of freedom for rotational motion (rotations in R x, R y, and R z directions) for each atom.
Absorptions bands in the Earth's atmosphere created by greenhouse gases and the resulting effects on transmitted radiation.. In spectroscopy, an absorption band is a range of wavelengths, frequencies or energies in the electromagnetic spectrum that are characteristic of a particular transition from initial to final state in a substance.
Rotational–vibrational spectroscopy is a branch of molecular spectroscopy that is concerned with infrared and Raman spectra of molecules in the gas phase.Transitions involving changes in both vibrational and rotational states can be abbreviated as rovibrational (or ro-vibrational) transitions.
The vibration theory of smell proposes that a molecule's smell character is due to its vibrational frequency in the infrared range. This controversial theory is an alternative to the more widely accepted docking theory of olfaction (formerly termed the shape theory of olfaction), which proposes that a molecule's smell character is due to a range of weak non-covalent interactions between its ...