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Solid properties Std enthalpy change of formation, Δ f H o solid? kJ/mol Standard molar entropy, S o solid? J/(mol K) Heat capacity, c p? J/(mol K) Liquid properties Std enthalpy change of formation, Δ f H o liquid-147.6 kJ/mol Standard molar entropy, S o liquid: 229.7 J/(mol K) Heat capacity, c p: 132.42 J/(mol K) –262 °C to –3 °C Gas ...
The butane used as a solvent for fragrance extraction does not contain these contaminants. [33] Butane gas can cause gas explosions in poorly ventilated areas if leaks go unnoticed and are ignited by spark or flame. [5] Purified butane is used as a solvent in the industrial extraction of cannabis oils.
For example, cyclobutane and methylcyclopropane are isomers of each other (C 4 H 8), but are not isomers of butane (C 4 H 10). Branched alkanes are more thermodynamically stable than their linear (or less branched) isomers. For example, the highly branched 2,2,3,3-tetramethylbutane is about 1.9 kcal/mol more stable than its linear isomer, n ...
Polar molecules must contain one or more polar bonds due to a difference in electronegativity between the bonded atoms. Molecules containing polar bonds have no molecular polarity if the bond dipoles cancel each other out by symmetry. Polar molecules interact through dipole-dipole intermolecular forces and hydrogen bonds.
In general, the hydroxyl group makes alcohols polar. Those groups can form hydrogen bonds to one another and to most other compounds. Owing to the presence of the polar OH alcohols are more water-soluble than simple hydrocarbons. Methanol, ethanol, and propanol are miscible in water. 1-Butanol, with a four-carbon chain, is moderately soluble.
Halogenating a hydrocarbon produces something that is not a hydrocarbon. It is a very common and useful process. Hydrocarbons with the same molecular formula but different structural formulae are called structural isomers. [1]: 625 As given in the example of 3-methylhexane and its higher homologues, branched hydrocarbons can be chiral.
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Volatility can also describe the tendency of a vapor to condense into a liquid or solid; less volatile substances will more readily condense from a vapor than highly volatile ones. [1] Differences in volatility can be observed by comparing how fast substances within a group evaporate (or sublimate in the case of solids) when exposed to the ...